One-Pot Synthesis of Thiocarbamide Esters: Construction of C-S Bonds under Transition-Metal-Free Conditions

被引：0
|
作者：
Deng, Shi-Hao [1 ]
Yu, Jun-Xia [1 ]
Xiao, Hua-Qing [5 ]
Dong, Zhi-Bing [1 ,2 ,3 ,4 ]
机构：
[1] Wuhan Inst Technol, Sch Chem & Environm Engn, Wuhan 430205, Peoples R China
[2] Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China
[3] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Peoples R China
[4] Wuhan Inst Technol, Minist Educ, Key Lab Green Chem Proc, Wuhan 430205, Peoples R China
[5] Hubei Greenhome Mat Technol, Xiantao 433000, Peoples R China
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 2022卷 / 46期
关键词：
C-S bond; One-Pot; Synthesis; Transition-Metal free; Thiocarbamide Esters; ARYLBORONIC ACIDS; THIOETHERS; CHLORIDES; DIARYL; THIOLS;
D O I：
10.1002/ejoc.202201167
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A convenient and effective method for the construction of C-S bond under transition-metal free conditions was reported. Thus, diverse thiocarbamide esters could be smoothly obtained in moderate to good yields from inexpensive and readily available starting materials, such as phenyl isothiocyanate, alcohols and benzyl halides. This method features mild conditions, easy operation, short reaction time and broad substrate scopes, providing a facile and convenient strategy for the preparation of some compounds with potential biological activities.
引用
收藏
页数：4
相关论文
共 50 条
  • [1] One-Pot Synthesis of 2-Arylindole Derivatives under Transition-Metal-Free Conditions
    Kraikruan, Panitan
    Rakchaya, Intouch
    Sang-aroon, Pattarapon
    Chuanopparat, Nutthawat
    Ngernmeesri, Paiboon
    SYNLETT, 2022, 33 (14) : 1443 - 1447
  • [2] One-pot transition-metal-free synthesis of alkynes and enynes
    Gu, Yuanyun
    Wu, Yu
    Wang, Yan-En
    Phadnis, Nidheesh
    Xiong, Dan
    Mao, Jianyou
    Walsh, Patrick J.
    CELL REPORTS PHYSICAL SCIENCE, 2024, 5 (08):
  • [3] One-Pot Transition-Metal-Free Synthesis of Alkynyl Amides
    Wu, Yu
    Satiro, Barbara G.
    Mao, Jianyou
    Walsh, Patrick J.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2025, 64 (03)
  • [4] One-pot synthesis of substituted indolo[1,2-a]quinolines under transition-metal-free conditions
    Thanetchaiyakup, Adisak
    Rattanarat, Hassayaporn
    Chuanopparat, Nutthawat
    Ngernmeesri, Paiboon
    TETRAHEDRON LETTERS, 2018, 59 (11) : 1014 - 1018
  • [5] Transition-metal-free one-pot synthesis of alkynyl selenides from terminal alkynes under aerobic and sustainable conditions
    Heredia, Adrian A.
    Penenory, Alicia B.
    BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2017, 13 : 910 - 918
  • [6] One-Pot Synthesis of Benzoxazole/Benzothiazole-Substituted Esters by Michael Addition: A Selective Construction of C-N/C-S Bonds
    Gong, Zhi-Ying
    Yang, Cheng-Li
    Wang, Dan
    Huang, Lang
    Dong, Zhi-Bing
    CATALYSTS, 2023, 13 (04)
  • [7] One-Pot Transition-Metal-Free Synthesis of π-Extended Bipolar Polyaromatic Hydrocarbons
    Bartkowski, Krzysztof
    Masoumifeshani, Emran
    Klimczak, Urszula
    Kotowska, Martyna
    Furman, Bartlomiej
    Foroutan-Nejad, Cina
    Lindner, Marcin
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2025, 64 (13)
  • [8] A One-Pot, Transition-Metal-Free Procedure for C-O, C-S, and C-N Bond Formation at the Benzylic Position of Methylarenes
    Shimojo, Hiroyuki
    Moriyama, Katsuhiko
    Togo, Hideo
    SYNTHESIS-STUTTGART, 2015, 47 (09): : 1280 - 1290
  • [9] Regiodivergent Halogenation of Vinylogous Esters: One-Pot, Transition-Metal-Free Access to Differentiated Haloresorcinols
    Chen, Xiaohong
    Martinez, Jenny S.
    Mohr, Justin T.
    ORGANIC LETTERS, 2015, 17 (02) : 378 - 381
  • [10] Facile synthesis of 4-quinolone derivatives via one-pot cascade reaction under transition-metal-free conditions
    Huang, Chao
    Guo, Jia-Hui
    Fu, Huang-Mei
    Yuan, Ming-Long
    Yang, Li-Juan
    TETRAHEDRON LETTERS, 2015, 56 (24) : 3777 - 3781
12345