Nitrite increases the enantioselectivity of sulfoxidation catalyzed by myoglobin derivatives in the presence of hydrogen peroxide

被引：6

作者：

Pironti, V

Nicolis, S

Monzani, E

Colonna, S

Casella, L

机构：

[1] Univ Pavia, Dipartimento Chim Gen, I-27100 Pavia, Italy

[2] Univ Milan, Ist Chim Organ Alessandro Marchesini, Fac Farm, I-20133 Milan, Italy

来源：

TETRAHEDRON | 2004年 / 60卷 / 37期

关键词：

asymmetric oxidation; myoglobin; nitrite; NMR; sulfoxidation;

D O I：

10.1016/j.tet.2004.06.097

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The effect of nitrite in the sulfoxidation of organic sulfides catalyzed by myoglobin (Mb) in the presence of hydrogen peroxide has been investigated. A general improvement in enantioselectivity was found for the reaction catalyzed by horse heart metMb and a series of sperm whale metMb derivatives including the wild type protein, the active site mutants T67K Mb, T67R Mb, T67R/S92D Mb, and the T67K Mb derivative reconstituted with the modified prosthetic group protohemin-L- histidine methyl ester. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：8153 / 8160

页数：8

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