RUTHENIUM-CATALYZED OXIDATION OF TERTIARY-AMINES WITH HYDROGEN-PEROXIDE IN THE PRESENCE OF METHANOL

被引：88
|
作者：
MURAHASHI, SI
NAOTA, T
MIYAGUCHI, N
NAKATO, T
机构：
[1] Department of Chemistry, Faculty of Engineering Science, Osaka University Machikaneyama, Toyonaka, Osaka
来源：
TETRAHEDRON LETTERS | 1992年 / 33卷 / 46期
关键词：
D O I：
10.1016/S0040-4039(00)60914-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Alpha-Methoxylation of tertiary amines can be performed by the ruthenium-catalyzed oxidation of tertiary amines with hydrogen peroxide in the presence of methanol. The reaction provides an efficient method for selective N-demethylation of tertiary methylamines and construction of quinoline skeletons.
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页码：6991 / 6994
页数：4
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