Novel fluoropolymer functionalized silsesquioxanes for nanoscale architecture of hybrid composites

被引：16
|
作者：
Suresh, S
Zhou, WS
Spraul, B
Laine, RM
Ballato, J
Smith, DW [1 ]
机构：
[1] Clemson Univ, Dept Chem, Clemson, SC 29631 USA
[2] Clemson Univ, Sch Mat Sci & Engn, Clemson, SC 29631 USA
[3] Clemson Univ, COMSET, Clemson, SC 29631 USA
[4] Univ Michigan, Ctr Macromol Sci & Engn, Dept Mat Sci & Engn, Ann Arbor, MI 48109 USA
来源：
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2004年 / 4卷 / 03期
关键词：
perfluorocyclobutyl polymers; silsesquioxane; inorganic-organic hybrid nanocomposites;
D O I：
10.1166/jnn.2004.033
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Condensation of octa(aminophenyl)silsesquioxane with 4-(trifluorovinyloxy)benzoyl chloride affords new fluoroolefin functionalized silsesquioxanes in good yield. The new octa-trifluorovinyl functionalized monomer undergoes thermal copolymerization with established trifluorovinyl aryl ether terminated perfluorocyclobutyl (PFCB) oligomers, giving the first example of silsesquioxane functionalized PFCB materials. The new hybrid polymers offer a versatile building block toward a variety of nanocomposite applications including low loss photonics.
引用
收藏
页码：250 / 253
页数：4
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