Novel fluoropolymer functionalized silsesquioxanes for nanoscale architecture of hybrid composites

被引：16

作者：

Suresh, S

Zhou, WS

Spraul, B

Laine, RM

Ballato, J

Smith, DW ^{[1
]}

机构：

[1] Clemson Univ, Dept Chem, Clemson, SC 29631 USA

[2] Clemson Univ, Sch Mat Sci & Engn, Clemson, SC 29631 USA

[3] Clemson Univ, COMSET, Clemson, SC 29631 USA

[4] Univ Michigan, Ctr Macromol Sci & Engn, Dept Mat Sci & Engn, Ann Arbor, MI 48109 USA

来源：

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2004年 / 4卷 / 03期

关键词：

perfluorocyclobutyl polymers; silsesquioxane; inorganic-organic hybrid nanocomposites;

D O I：

10.1166/jnn.2004.033

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Condensation of octa(aminophenyl)silsesquioxane with 4-(trifluorovinyloxy)benzoyl chloride affords new fluoroolefin functionalized silsesquioxanes in good yield. The new octa-trifluorovinyl functionalized monomer undergoes thermal copolymerization with established trifluorovinyl aryl ether terminated perfluorocyclobutyl (PFCB) oligomers, giving the first example of silsesquioxane functionalized PFCB materials. The new hybrid polymers offer a versatile building block toward a variety of nanocomposite applications including low loss photonics.

引用

页码：250 / 253

页数：4

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