Di-tert- butyl Peroxide Promoted Direct C-H Arylation of Unactivated Arenes with Aryl Halides

被引：16
|
作者：
Zhu, Yi-Wei [1 ]
Yi, Wen-Bin [1 ]
Qian, Jin-Long [1 ]
Cai, Chun [1 ]
机构：
[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China
来源：
CHEMCATCHEM | 2014年 / 6卷 / 03期
基金：
中国国家自然科学基金;
关键词：
aromatic substitution; arylation; peroxides; radicals; transition-metal free; CATALYZED DIRECT ARYLATION; HOMOLYTIC AROMATIC-SUBSTITUTION; BOND ACTIVATION; COUPLING REACTIONS; BENZENE; FUNCTIONALIZATION; BUTOXIDE;
D O I：
10.1002/cctc.201301058
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Di-tert-butyl peroxide can smoothly promote the coupling of aryl halides with benzene derivatives without the aid of transition-metal catalysts through a chain homolytic aromatic substitution mechanism in the presence of potassium tert-butoxide.
引用
收藏
页码：733 / 735
页数：3
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