Di-tert- butyl Peroxide Promoted Direct C-H Arylation of Unactivated Arenes with Aryl Halides

被引：16
|
作者：
Zhu, Yi-Wei [1 ]
Yi, Wen-Bin [1 ]
Qian, Jin-Long [1 ]
Cai, Chun [1 ]
机构：
[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China
来源：
CHEMCATCHEM | 2014年 / 6卷 / 03期
基金：
中国国家自然科学基金;
关键词：
aromatic substitution; arylation; peroxides; radicals; transition-metal free; CATALYZED DIRECT ARYLATION; HOMOLYTIC AROMATIC-SUBSTITUTION; BOND ACTIVATION; COUPLING REACTIONS; BENZENE; FUNCTIONALIZATION; BUTOXIDE;
D O I：
10.1002/cctc.201301058
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Di-tert-butyl peroxide can smoothly promote the coupling of aryl halides with benzene derivatives without the aid of transition-metal catalysts through a chain homolytic aromatic substitution mechanism in the presence of potassium tert-butoxide.
引用
收藏
页码：733 / 735
页数：3
相关论文
共 50 条
  • [31] Improving the sustainability of the ruthenium-catalysed N-directed C-H arylation of arenes with aryl halides
    Findlay, Michael T.
    Hogg, Ashley S.
    Douglas, James J.
    Larrosa, Igor
    GREEN CHEMISTRY, 2023, 25 (06) : 2394 - 2400
  • [32] Orthogonal Palladium-Catalyzed Direct C-H Bond Arylation of Heteroaromatics with Aryl Halides
    Theveau, Laure
    Schneider, Cedric
    Fruit, Corinne
    Hoarau, Christophe
    CHEMCATCHEM, 2016, 8 (20) : 3183 - 3194
  • [33] Ligand-Promoted Direct C-H Arylation of Simple Arenes: Evidence for a Cooperative Bimetallic Mechanism
    Kim, Jaewoon
    Hong, Soon Hyeok
    ACS CATALYSIS, 2017, 7 (05): : 3336 - 3343
  • [34] tert-Butoxide-promoted Coupling of Aryl Iodides with Arenes Using Di-tert-butyl Hyponitrite as an Initiator
    Kiriyama, Kazuya
    Shirakawa, Eiji
    CHEMISTRY LETTERS, 2017, 46 (12) : 1757 - 1759
  • [35] Directing group assisted rhodium-catalyzed formal C-H arylation and carbonylative arylation of arenes with aryl halides in the presence of CO
    Teng, Houyun
    Shao, Xiaoyuan
    Zhang, Zheng-Feng
    Yang, Ke-Fang
    Su, Ming-Der
    Xu, Li-Wen
    Yang, Lei
    JOURNAL OF CATALYSIS, 2024, 429
  • [36] Direct arylation via cleavage of activated and unactivated C-H bonds
    Miura, M
    Nomura, M
    CROSS-COUPLING REACTIONS: A PRACTICAL GUIDE, 2002, 219 : 211 - 241
  • [37] Palladium-catalysed C-H arylation of benzophospholes with aryl halides
    Xu, Shibo
    Nishimura, Kazutoshi
    Saito, Kosuke
    Hirano, Koji
    Miura, Masahiro
    CHEMICAL SCIENCE, 2022, 13 (36) : 10950 - 10960
  • [38] Ru-Catalyzed C-H Arylation of Fluoroarenes with Aryl Halides
    Simonetti, Marco
    Perry, Gregory J. P.
    Cambeiro, Xacobe C.
    Julia-Hernandez, Francisco
    Arokianathar, Jude N.
    Larrosa, Igor
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (10) : 3596 - 3606
  • [39] Ru-catalyzed C-H arylation of fluoroarenes with aryl halides
    Simonetti, Marco
    Perry, Gregory
    Cambeiro, Xacobe
    Julia-Hernandez, Francisco
    Arokianathar, Jude
    Larrosa, Igor
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 252
  • [40] Ru-Catalyzed C-H Arylation of Fluoroarenes with Aryl Halides
    Larrosa, Igor (igor.larrosa@manchester.ac.uk), 1600, American Chemical Society (138):
12345