Simple Preparation, Structure and Conductivity of Nickel(II) Benzenetricarboxylate Ni3(BTC)2•12H2O

被引：0
|
作者：
Tan Hai-Yan [1 ]
Liu Cheng [1 ]
Wang Zhao-Hui [1 ]
Wu Jin-Ping [1 ]
机构：
[1] China Univ Geosci, Fac Mat Sci & Chem, Sustainable Energy Lab, Wuhan 430074, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 33卷 / 03期
关键词：
metal-organic framework; solvothermal synthesis; mixed solution; semiconducting properties; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; CATALYSIS; ROUTE;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Proton-conductive crystalline metal-organic framework nickel(II) benzenetricarboxylate Ni-3(BTC)(2)center dot 12H(2)O(MOF-Ni) was prepared by the reaction of nickel(II) nitrate and 1,3,5-benzenetricarboxylic(BTC) acid in a mixed solvent of N,N-dimethylformamide(DMF)/C2H5OH/H2O (1:1:1, v/v) at low temperature and short reaction time. It was characterized by thermogravimetric analyses (TG), FT-IR and N-2 adsorption-desorption. Single-crystal X-ray diffraction analysis indicated that the complex belongs to monoclinic system, space group C2 with a = 17.407(6), b = 12.878(5), c = 6.542(2) angstrom, beta = 112.07 degrees, V = 1359.0(8) angstrom(3), D-c = 1.971 g/cm(3), mu = 2.166 mm(-1) and Z = 2. Linear polarization resistance (LPR) analysis showed that the complex possesses semiconducting properties.
引用
收藏
页码：401 / 406
页数：6
相关论文
共 50 条
  • [41] Crystal structure of diaquabis(6-hydroxy-3-pyridazinecarboxylato)nickel(II) dihydrate, Ni(H2O)2(C5H3N2O3)2 • 2H2O
    Xiao, Bo
    Zhang, Xia
    Yang, Li-Jun
    Wang, Yu-Ting
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2011, 226 (01): : 23 - 24
  • [42] First example of photomagnetic effects in ionic pairs [Ni(bipy)3]2[Mo(CN)8] • 12H2O
    Korzeniak, Tomasz
    Mathoniere, Corine
    Kaiba, Abdellah
    Guionneau, Philippe
    Koziel, Marcin
    Sieklucka, Barbara
    INORGANICA CHIMICA ACTA, 2008, 361 (12-13) : 3500 - 3504
  • [43] The first 3-D ferrimagnetic nickel fumarate with an open framework:: [Ni3(OH)2(O2C-C2H2-CO2)(H2O)4]•2H2O
    Guillou, N
    Pastre, S
    Livage, C
    Férey, G
    CHEMICAL COMMUNICATIONS, 2002, (20) : 2358 - 2359
  • [44] Preparation, spectral and thermal properties of two tetracyanopalladates(II) of nickel(II) and the crystal structure of [Ni(en)3][Pd(CN)4]•H2O
    Bubanec, J
    Cernák, J
    Potocñák, I
    Drábik, M
    Lipkowski, J
    CHEMICAL PAPERS, 2004, 58 (04): : 224 - 231
  • [45] 含能配合物[Ni3（3-atrz）6（H2O）6][Ni（pda）2]3·12H2O的合成、结构及其对推进剂主要组份热分解行为的影响
    高胜利
    陈三平
    杨奇
    周春生
    商洛学院学报, 2009, 23 (04) : 3 - 10
  • [46] Investigating the effect of graphene nanoplatelets on the thermal conductivity of KAI(SO4)2 • 12H2O
    Sun, Mingjie
    Liu, Liqiang
    Ma, Fukun
    Jing, Min
    Cui, Kaixuan
    Lin, Liangkan
    MATERIALS RESEARCH EXPRESS, 2018, 5 (04):
  • [47] Dye sensitized photocatalytic degradation of congo red and rhodamine B by 1,3,5-Benzenetricarboxylic acid based metal organic frameworks Ni3(BTC)2.12H2O, (Ni0.8Co0.2)3(BTC)2.12H2O and Cu3(BTC)2 under visible light
    Karuppiah, Kavitha
    Raju, Anushree
    Natarajan, Anuradha
    Mohan, Swedha
    Subramani, Dhinakaran
    Rajendran, Kumaran
    Mahalingam, Vanjinathan
    Arumugam, Gopalakrishnan
    Prabu, Samikannu
    Chiang, Kung-Yuh
    Rajaraman, Vasanthi
    RESULTS IN CHEMISTRY, 2025, 14
  • [48] Ultrasound-assisted coating of silk yarn with nano-porous Co3(BTC)2•12H2O with iodine adsorption affinity
    Shamaei, Shabnam
    Abbasi, Amir Reza
    Noori, Nourolah
    Rafiee, Ezzat
    Azadbakht, Azadeh
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2013, 431 : 66 - 72
  • [49] Crystal structure analysis and chiral recognition study of Δ-[Ru(bpy)2(py)2][(+)-O,O′-dibenzoyl-D-tartrate]•12H2O and Λ-[Ru(bpy)2(py)2][(-)-O,O′-dibenzoyl-L-tartrate]•12H2O
    Kolp, B
    Viebrock, H
    von Zelewsky, A
    Abeln, D
    INORGANIC CHEMISTRY, 2001, 40 (06) : 1196 - 1198
  • [50] Thermal decomposition of K2O•CaO•4B2O3•12H2O
    Jing, Y
    Jia, YZ
    Gao, SY
    Wang, HD
    Yu, SY
    THERMOCHIMICA ACTA, 2001, 374 (01) : 51 - 54
12345