Simple Preparation, Structure and Conductivity of Nickel(II) Benzenetricarboxylate Ni3(BTC)2•12H2O

被引：0
|
作者：
Tan Hai-Yan [1 ]
Liu Cheng [1 ]
Wang Zhao-Hui [1 ]
Wu Jin-Ping [1 ]
机构：
[1] China Univ Geosci, Fac Mat Sci & Chem, Sustainable Energy Lab, Wuhan 430074, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 33卷 / 03期
关键词：
metal-organic framework; solvothermal synthesis; mixed solution; semiconducting properties; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; CATALYSIS; ROUTE;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Proton-conductive crystalline metal-organic framework nickel(II) benzenetricarboxylate Ni-3(BTC)(2)center dot 12H(2)O(MOF-Ni) was prepared by the reaction of nickel(II) nitrate and 1,3,5-benzenetricarboxylic(BTC) acid in a mixed solvent of N,N-dimethylformamide(DMF)/C2H5OH/H2O (1:1:1, v/v) at low temperature and short reaction time. It was characterized by thermogravimetric analyses (TG), FT-IR and N-2 adsorption-desorption. Single-crystal X-ray diffraction analysis indicated that the complex belongs to monoclinic system, space group C2 with a = 17.407(6), b = 12.878(5), c = 6.542(2) angstrom, beta = 112.07 degrees, V = 1359.0(8) angstrom(3), D-c = 1.971 g/cm(3), mu = 2.166 mm(-1) and Z = 2. Linear polarization resistance (LPR) analysis showed that the complex possesses semiconducting properties.
引用
收藏
页码：401 / 406
页数：6
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