Electric field of Ions in solution probed by hyper-Rayleigh scattering

被引：28
|
作者：
Shelton, David P. [1 ]
机构：
[1] Univ Nevada, Dept Phys & Astron, Las Vegas, NV 89154 USA
来源：
JOURNAL OF CHEMICAL PHYSICS | 2009年 / 130卷 / 11期
关键词：
diffusion; dissolving; electric fields; fluctuations; heavy water; liquid structure; potassium compounds; Rayleigh scattering; MULTIPOLE POLARIZABILITIES; LIGHT-SCATTERING; REFRACTIVE-INDEX; DIPOLE-MOMENT; WATER; H2O; HYPERPOLARIZABILITIES; TEMPERATURE; DEPENDENCE; DYNAMICS;
D O I：
10.1063/1.3089882
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The electric field of dissolved ions accounts for the narrow spike at zero frequency shift, with the polarization signature of a polar longitudinal collective mode, in the high resolution hyper-Rayleigh light scattering (HRS) spectrum for liquid water and other polar solvents. This peak in the HRS spectrum probes both the structure factor and the fluctuation time for the ion charge density in solution. The experimental results for KCl-D2O solutions are consistent with the Debye-Huckel charge structure factor and determine the diffusion coefficient and static local field factor.
引用
收藏
页数：4
相关论文
共 50 条
  • [21] Hyper-Rayleigh scattering in centrosymmetric systems
    Williams, Mathew D.
    Ford, Jack S.
    Andrews, David L.
    JOURNAL OF CHEMICAL PHYSICS, 2015, 143 (12):
  • [22] Long-range orientation correlation in dipolar liquids probed by hyper-Rayleigh scattering
    Shelton, David P.
    JOURNAL OF CHEMICAL PHYSICS, 2015, 143 (13):
  • [23] Silver-island films probed by hyper-Rayleigh scattering and atomic force microscopy
    Didenko, NV
    Kim, EM
    Muzychenko, DA
    Nikulin, AA
    Aktsipetrov, OA
    APPLIED PHYSICS B-LASERS AND OPTICS, 2002, 74 (7-8): : 647 - 651
  • [24] Silver-island films probed by hyper-Rayleigh scattering and atomic force microscopy
    N.V. Didenko
    E.M. Kim
    D.A. Muzychenko
    A.A. Nikulin
    O.A. Aktsipetrov
    Applied Physics B, 2002, 74 : 647 - 651
  • [25] Probing molecular self-assembly by hyper-Rayleigh scattering in solution
    Ray, P. C.
    Das, P. K.
    Chemical Physics Letters, 281 (04):
  • [26] Third-order hyper-Rayleigh scattering in an azobenzene dye solution
    Yamada, T
    Mashiko, S
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 2000, 39 (10B): : L1060 - L1063
  • [27] Probing molecular self-assembly by hyper-Rayleigh scattering in solution
    Ray, PC
    Das, PK
    CHEMICAL PHYSICS LETTERS, 1997, 281 (4-6) : 243 - 246
  • [28] ON ROTATION OF THE POLARIZATION ELLIPSE IN ELECTRIC-DIPOLE HYPER-RAMAN AND HYPER-RAYLEIGH SCATTERING
    KOZIEROWSKI, M
    MOLECULAR PHYSICS, 1985, 54 (01) : 197 - 201
  • [29] Mechanisms universally permitting hyper-Rayleigh scattering
    Williams, Mathew D.
    Ford, Jack S.
    Andrews, David L.
    NONLINEAR FREQUENCY GENERATION AND CONVERSION: MATERIALS, DEVICES, AND APPLICATIONS XIV, 2015, 9347
  • [30] Hyper-Rayleigh scattering of neutral and charged helicenes
    Botek, E
    Spassova, M
    Champagne, B
    Asselberghs, I
    Persoons, A
    Clays, K
    CHEMICAL PHYSICS LETTERS, 2005, 412 (4-6) : 274 - 279
12345