Electric field of Ions in solution probed by hyper-Rayleigh scattering

被引：28
|
作者：
Shelton, David P. [1 ]
机构：
[1] Univ Nevada, Dept Phys & Astron, Las Vegas, NV 89154 USA
来源：
JOURNAL OF CHEMICAL PHYSICS | 2009年 / 130卷 / 11期
关键词：
diffusion; dissolving; electric fields; fluctuations; heavy water; liquid structure; potassium compounds; Rayleigh scattering; MULTIPOLE POLARIZABILITIES; LIGHT-SCATTERING; REFRACTIVE-INDEX; DIPOLE-MOMENT; WATER; H2O; HYPERPOLARIZABILITIES; TEMPERATURE; DEPENDENCE; DYNAMICS;
D O I：
10.1063/1.3089882
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The electric field of dissolved ions accounts for the narrow spike at zero frequency shift, with the polarization signature of a polar longitudinal collective mode, in the high resolution hyper-Rayleigh light scattering (HRS) spectrum for liquid water and other polar solvents. This peak in the HRS spectrum probes both the structure factor and the fluctuation time for the ion charge density in solution. The experimental results for KCl-D2O solutions are consistent with the Debye-Huckel charge structure factor and determine the diffusion coefficient and static local field factor.
引用
收藏
页数：4
相关论文
共 50 条
  • [11] Hyper-Rayleigh scattering for solution phase structure determination
    Clays, Koen
    Therien, Michael J.
    Hennrich, Gunther
    LINEAR AND NONLINEAR OPTICS OF ORGANIC MATERIALS VIII, 2008, 7049
  • [12] Rayleigh and hyper-Rayleigh scatterings in solution
    Xu, WX
    OPTICS AND LASER TECHNOLOGY, 2004, 36 (02): : 155 - 162
  • [13] Surface heterogeneity in Au-Ag nanoparticles probed by hyper-Rayleigh scattering
    Russier-Antoine, Isabelle
    Bachelier, Guillaume
    Sabloniere, Virginie
    Duboisset, Julien
    Benichou, Emmanuel
    Jonin, Christian
    Bertorelle, Franck
    Brevet, Pierre-Francois
    PHYSICAL REVIEW B, 2008, 78 (03)
  • [14] The symmetry of functionalized poly(propylene imine) dendrimers probed with hyper-Rayleigh scattering
    Put, EJH
    Clays, K
    Persoons, A
    Biemans, HAM
    Jansen, JFGA
    Kurvers, R
    Luijkx, CPM
    Meijer, EW
    NONLINEAR OPTICAL PROPERTIES OF ORGANIC MATERIALS IX, 1996, 2852 : 122 - 131
  • [15] Water-water correlations in electrolyte solutions probed by hyper-Rayleigh scattering
    Shelton, David P.
    JOURNAL OF CHEMICAL PHYSICS, 2017, 147 (21):
  • [16] The symmetry of functionalized poly(propylene imine) dendrimers probed with hyper-Rayleigh scattering
    Put, RJH
    Clays, K
    Persoons, A
    Biemans, HAM
    Luijkx, CPM
    Meijer, EW
    CHEMICAL PHYSICS LETTERS, 1996, 260 (1-2) : 136 - 141
  • [17] Hyper-Rayleigh scattering as a means of monitoring crystal nucleation in solution
    D'Arrigo, M. C.
    Cruickshank, F. R.
    Pugh, D.
    Sherwood, J. N.
    Wallis, J. D.
    Mackenzie, C.
    Hayward, D.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (32) : 3761 - 3766
  • [18] Hyper-Rayleigh scattering of CdS nanoparticles with different surfaces in solution
    Wang, X
    Zhang, Y
    Shen, YC
    Li, M
    Fu, DG
    Lu, ZH
    Cui, YP
    MICRO- AND NANO-PHOTONIC MATERIALS AND DEVICES, 2000, 3937 : 123 - 131
  • [19] Magnetic-field-induced coherence in hyper-Rayleigh scattering
    Kolmychek, I. A.
    Murzina, T. V.
    Nikulin, A. A.
    Aktsipetrov, O. A.
    JETP LETTERS, 2012, 95 (03) : 127 - 131
  • [20] Magnetic-field-induced coherence in hyper-Rayleigh scattering
    I. A. Kolmychek
    T. V. Murzina
    A. A. Nikulin
    O. A. Aktsipetrov
    JETP Letters, 2012, 95 : 127 - 131
12345