A cadmium(II) coordination polymer:: Crystal structure and fluorescent property of [CdCl2(4,4′-bipyridine)]∞

被引：0
|
作者：
Lou, BY [1 ]
Wang, RH [1 ]
Xu, Y [1 ]
Yuan, DQ [1 ]
Zhou, YF [1 ]
Hong, MC [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2004年 / 23卷 / 07期
关键词：
cadmium(II); coordination polymer; crystal structure; fluorescence;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of L-histidine, CdCl(2)(.)2.5H(2)O and 4,4'-bipyridine in methane/water gave rise to a two-dimensional coordination polymer [CdCl2(4,4'-bipyridine)](infinity) which has been characterized by single-crystal X-ray diffraction. The polymer crystallizes in the orthorhombic system, space group Cmmm with a = 12.083 (7), b = 11.771(7), c = 3.781(2) Angstrom, V = 537.8(6) Angstrom(3), Z = 2, C10H8N2CdCl2, M-r = 339.48, D-c = 2.097 g/cm(3), F(000) = 328 and mu(MoKalpha) = 2.490 mm(-1). The final R = 0.0658 and wR = 0.1398 for 257 observed reflections with I greater than or equal to 2sigma(I).
引用
收藏
页码：747 / 750
页数：4
相关论文
共 50 条
  • [31] A 2D Brickwall-like Copper(Ⅱ) Coordination Polymer Based on Phenyliminodiacetate and 4,4?-Bipyridine: Synthesis,Crystal Structure and Magnetic Property
    王小兵
    陆政安
    卢文贯
    Chinese Journal of Structural Chemistry, 2015, 34 (09) : 1410 - 1416
  • [32] (4,4′-bipyridine)dichloromanganese(II), a two-dimensional coordination polymer
    Chippindale, Ann M.
    Cowley, Andrew R.
    Peacock, Katherine J.
    Acta Crystallographica, Section C: Crystal Structure Communications, 2000, 56 (06) : 651 - 652
  • [33] Synthesis, crystal structure and luminescent properties of a new 3D coordination polymer constructed by Cd(II) with 4,4′-oxybis(benzoate) and 4,4′-bipyridine
    Ma, Yi
    He, Yongke
    Zhang, Litian
    Wang, Xiaofang
    Gao, Jingqun
    Han, Zhengbo
    STRUCTURAL CHEMISTRY, 2007, 18 (06) : 1005 - 1009
  • [34] Synthesis, crystal structure and luminescent properties of a new 3D coordination polymer constructed by Cd(II) with 4,4′-oxybis(benzoate) and 4,4′-bipyridine
    Yi Ma
    Yongke He
    Litian Zhang
    Xiaofang Wang
    Jingqun Gao
    Zhengbo Han
    Structural Chemistry, 2007, 18 : 1005 - 1009
  • [35] One-dimensional network of zinc(II) coordination polymer with 4,4′-bipyridine (4,4′-bipy)
    Kim, Jungsook
    Lee, Uk
    Koo, Bon Kweon
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2006, 27 (06): : 918 - 920
  • [36] Crystal structure of bis(4,4'-bipyridine)zinc(II) succinate
    Yao, J
    Fu, YL
    Zheng, SL
    Chen, XM
    Ng, SW
    MAIN GROUP METAL CHEMISTRY, 2001, 24 (05) : 289 - 290
  • [37] Crystal structure of ∞2[Cu2I2(μ-4,4′-bipyridine)] and investigations on the thermal decomposition of CuX-4,4′-bipyridine coordination polymers
    Näther, C
    Jess, I
    MONATSHEFTE FUR CHEMIE, 2001, 132 (08): : 897 - 910
  • [38] Synthesis, crystal structure, and fluorescent property of a 1D Pb(II) coordination polymer containing unique helical chains based on 4,4′-oxydiphthalate
    Wang, Jun
    Ju, Wen-Wen
    Xue, Yun-Shan
    Tao, Jian-Qing
    INORGANIC AND NANO-METAL CHEMISTRY, 2017, 47 (04) : 488 - 492
  • [39] A Three-Interpenetrating Cobalt(II) Coordination Polymer Based on 4,4′-Azodibenzoic acid and 4,4′-Bipyridine: Solvothermal Synthesis, Crystal Structure and Thermal Stability Properties
    Han Yin-Feng
    Liu Tao
    Duan Wen-Zeng
    Wu Ren-Tao
    Li Ji-Kun
    Li Xiao-Yan
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2012, 28 (01) : 149 - 152
  • [40] THE STRUCTURE OF CADMIUM BIS(ISOPROPYLXANTHATE)-4,4'-BIPYRIDINE
    ABRAHAMS, BF
    HOSKINS, BF
    WINTER, G
    AUSTRALIAN JOURNAL OF CHEMISTRY, 1990, 43 (10) : 1759 - 1765
12345