A cadmium(II) coordination polymer:: Crystal structure and fluorescent property of [CdCl2(4,4′-bipyridine)]∞

被引：0
|
作者：
Lou, BY [1 ]
Wang, RH [1 ]
Xu, Y [1 ]
Yuan, DQ [1 ]
Zhou, YF [1 ]
Hong, MC [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2004年 / 23卷 / 07期
关键词：
cadmium(II); coordination polymer; crystal structure; fluorescence;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of L-histidine, CdCl(2)(.)2.5H(2)O and 4,4'-bipyridine in methane/water gave rise to a two-dimensional coordination polymer [CdCl2(4,4'-bipyridine)](infinity) which has been characterized by single-crystal X-ray diffraction. The polymer crystallizes in the orthorhombic system, space group Cmmm with a = 12.083 (7), b = 11.771(7), c = 3.781(2) Angstrom, V = 537.8(6) Angstrom(3), Z = 2, C10H8N2CdCl2, M-r = 339.48, D-c = 2.097 g/cm(3), F(000) = 328 and mu(MoKalpha) = 2.490 mm(-1). The final R = 0.0658 and wR = 0.1398 for 257 observed reflections with I greater than or equal to 2sigma(I).
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页码：747 / 750
页数：4
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