Liquid phase oxidation reactions by peroxides in the presence of vanadium complexes

被引：158
|
作者：
Conte, V [1 ]
DiFuria, F [1 ]
Licini, G [1 ]
机构：
[1] UNIV PADUA, DIPARTIMENTO CHIM ORGAN, CNR, CTR MECCAN REAZIONI ORGAN, I-35131 PADUA, ITALY
来源：
APPLIED CATALYSIS A-GENERAL | 1997年 / 157卷 / 1-2期
关键词：
peroxovanadium complexes; catalytic oxidations; hydrogen peroxide; alkyl hydroperoxides;
D O I：
10.1016/S0926-860X(97)00023-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The reaction of vanadium (V) derivatives with hydrogen peroxide or with alkyl hydroperoxides leads to peroxovanadium complexes which are effective and selective oxidants of organic and inorganic substrates either under stoichiometric or catalytic conditions. Examples of synthetically significant oxidations of various classes of organic compounds are reported together with details on the commonly accepted mechanisms operating. When possible a comparison is made between peroxovanadium complexes of other d(0) metal derivative, e.g. Ti(IV), Mo(VI) and W(VI).
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页码：335 / 361
页数：27
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