Synthesis of dialkyl peroxides in the presence of polyethylene glycol or its derivatives as phase-transfer catalyst in liquid-liquid-liquid system

被引：19

作者：

Baj, Stefan ^{[1
]}

Siewniak, Agnieszka ^{[1
]}

机构：

[1] Silesian Tech Univ, Chair Chem Organ Technol & Petr Chem, PL-44100 Gliwice, Poland

来源：

APPLIED CATALYSIS A-GENERAL | 2007年 / 321卷 / 02期

关键词：

dialkyl peroxides; hydroperoxides; phase-transfer catalysts;

D O I：

10.1016/j.apcata.2007.01.049

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Synthesis of dialkyl peroxides in the presence of polyethylene glycol or its derivatives (PEG) as phase-transfer catalyst in liquid-liquid-liquid system was investigated. Conditions for forming a third-liquid phase, rich in phase-transfer catalyst were determined and included the amount and concentration of NaOH in the aqueous phase and the kind of organic solvent. The effect of chain length of PEG and possibility of catalyst recycling was also examined. Selected dialkyl peroxides were obtained in high yields. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：175 / 179

页数：5

共 50 条

[1] Tr-liquid system in the synthesis of dialkyl peroxides using tetraalkylammonium salts as phase-transfer catalysts
Baj, Stefan
Siewniak, Agnieszka
APPLIED CATALYSIS A-GENERAL, 2010, 385 (1-2) : 208 - 213
[2] Selectivity Engineering in Synthesis of 4-Benzyloxy Propiophenone Using Liquid-Liquid-Liquid Phase-Transfer Catalysis
Yadav, Ganapati D.
Sowbna, P. R.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (08) : 3256 - 3264
[3] Polyethylene glycol (PEG) as polymeric support and phase-transfer catalyst in the soluble polymer liquid phase synthesis of α-amino esters
Sauvagnat, B
Lamaty, F
Lazaro, R
Martinez, J
TETRAHEDRON LETTERS, 1998, 39 (08) : 821 - 824
[4] Synthesis of butyl salicylate by phase-transfer catalysis with dual-site phase-transfer catalyst and ionic liquid in tri-liquid system
Yang, Hung-Ming
Hung, Yu-Hung
Tu, Chi-Yuan
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2014, 45 (04) : 1421 - 1427
[5] Synthesis of triphenyl phosphate and benzyl benzoate with phase-transfer catalyst in heterogeneous liquid-liquid reaction system
Asai, Satoru
Nakamura, Hidemi
Tanabe, Mitsunori
Sakamoto, Kenji
Industrial and Engineering Chemistry Research, 1994, 33 (07): : 1687 - 1691
[6] SYNTHESIS OF HIPPURIC-ACID WITH INVERSE PHASE-TRANSFER CATALYST IN A HETEROGENEOUS LIQUID-LIQUID REACTION SYSTEM
ASAI, S
NAKAMURA, H
OKADA, W
YAMADA, M
CHEMICAL ENGINEERING SCIENCE, 1995, 50 (06) : 943 - 949
[7] SYNTHESIS OF TRIPHENYL PHOSPHATE AND BENZYL BENZOATE WITH PHASE-TRANSFER CATALYST IN HETEROGENEOUS LIQUID-LIQUID REACTION SYSTEM
ASAI, S
NAKAMURA, H
TANABE, M
SAKAMOTO, K
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1994, 33 (07) : 1687 - 1691
[8] Synthesis of dialkyl peroxides in the presence of polymer-supported phase-transfer catalysts
Baj, Stefan
Siewniak, Agnieszka
Socha, Beata
APPLIED CATALYSIS A-GENERAL, 2006, 309 (01) : 85 - 90
[9] Facile Synthesis of Ferrocenylchalcone Promoted by Ionic Liquid or Phase-Transfer Catalyst
Zhao, Haiying
Yin, Fengnan
Yu, Lingyan
Li, Baoguo
Bian, Zhanxi
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2016, 36 (05) : 1118 - 1121
[10] POLYETHYLENE-GLYCOL DERIVATIVES AS COMPLEXING AGENTS AND PHASE-TRANSFER CATALYSTS .4. BEHAVIOR OF PHASE-TRANSFER CATALYSTS IN SOLID LIQUID-PHASE EQUILIBRIA
SZABO, GT
ARANYOSI, K
TOKE, L
ACTA CHIMICA ACADEMIAE SCIENTARIUM HUNGARICAE, 1982, 110 (02): : 215 - 224

← 1 2 3 4 5 →