Photocatalytic hydrogen production from water using porous material [Ru2(p-BDC)2]n

被引:210
|
作者
Kataoka, Yusuke [1 ]
Sato, Konomi [1 ]
Miyazaki, Yuhei [1 ]
Masuda, Kazuki [1 ]
Tanaka, Hiroshi [1 ]
Naito, Shuichi [2 ]
Mori, Wasuke [1 ]
机构
[1] Kanagawa Univ, Fac Sci, Dept Chem, Kanagawa 2591293, Japan
[2] Kanagawa Univ, Fac Engn, Dept Appl Chem, Kanagawa 2218686, Japan
关键词
GAS-OCCLUSION PROPERTIES; TRANS-TRANS-MUCONATE; DICARBOXYLATES FUMARATE; CATALYTIC PERFORMANCE; MICROPOROUS MATERIALS; POLYMER; TEREPHTHALATE; RUTHENIUM; COMPLEX; DESIGN;
D O I
10.1039/b814539c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We have detected the first example of open porous metal-organic frameworks (MOFs) that functions as an activity site for the reduction of water into hydrogen molecules in the presence of Ru(bpy)(3)(2+), MV2+, and EDTA-2Na under visible light irradiation. This activity is highly efficient: the turnover number based on MOFs and the apparent quantum yield are 8.16 and 4.82%, respectively. Furthermore, this material enables the adsorption of various gases into its pores; its hydrogen uptake capacity is 1.2 wt% at 77.4 K.
引用
收藏
页码:397 / 400
页数:4
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