Photocatalytic hydrogen production using TiO2-Pt aerogels

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作者
Puskelova, Jarmila [1 ,7 ]
Baia, Lucian [2 ,3 ]
Vulpoi, Adriana [2 ,3 ]
Baia, Monica [2 ,3 ]
Antoniadou, Maria [1 ]
Dracopoulos, Vassilios [4 ]
Stathatos, Elias [5 ]
Gabor, Kovacs [6 ]
Pap, Zsolt [6 ]
Danciu, Virginia [6 ]
Lianos, Panagiotis [1 ,4 ]
机构
[1] [1,Puskelova, Jarmila
[2] 2,Baia, Lucian
[3] 2,Vulpoi, Adriana
[4] 2,Baia, Monica
[5] Antoniadou, Maria
[6] Dracopoulos, Vassilios
[7] Stathatos, Elias
[8] Gabor, Kovacs
[9] Pap, Zsolt
[10] Danciu, Virginia
[11] 1,Lianos, Panagiotis
来源
Lianos, P. (lianos@upatras.gr) | 1600年 / Elsevier B.V.卷 / 242期
关键词
TiO2-Pt aerogel composites have been synthesized by mixing sol-gel titania with Pt colloidal suspensions followed by supercritical drying. The highest specific surface achieved with these materials ranged between 550 and 600m2g-1 before annealing and stayed relatively high; i.e; 162m2g-1; after calcination. The concentration of Pt nanoparticles ranged between 0.3 and 1.0wt.% while their size ranged between 5.75 and 6.5nm. These composites were employed as photocatalysts for room-temperature photocatalytic reforming of ethanol and hydrogen production. The highest hydrogen production rate; 7.2mmolH2h-1g-1; was obtained in the case of the smallest and most concentrated metal nanoparticles underlying the importance of the number of active sites on the TiO2-Pt composites. This rate of hydrogen production is relatively high and reflects the relatively high specific surface of the employed photocatalysts. © 2013 Elsevier B.V;
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页码:96 / 101
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