Spectroscopic study on the photophysical properties of lanthanide complexes with 2,2′-bipyridine-N,N′-dioxide

被引：68
|
作者：
Yan, B [1 ]
Song, YS [1 ]
机构：
[1] Tongji Univ, Dept Chem, Shanghai 200092, Peoples R China
来源：
JOURNAL OF FLUORESCENCE | 2004年 / 14卷 / 03期
关键词：
lanthanide complexes; 2,2 '-bipyridine-N,N '-dioxide; photophysical property; energy tranfer; fluorescence;
D O I：
10.1023/B:JOFL.0000024561.55183.26
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
Five novel lanthanide (Eu3+, Tb3+, Gd3+, Sm3+ and Dy3+) complexes with 2, 2'-bipyridine- N, N'-dioxide (bipyO(2)) were synthesized and characterized by elemental analysis, IR spectrum. The triplet state energy of bipy O-2 was determined to be 22275 cm(-1) with the phosphorescence spectrum of bipy O-2 and its gadolinium complex. The photophysical properties of these complexes indicated that the triplet state energy of the ligand is suitable for the sensitization of the luminescence of Eu3+, Tb3+, Sm3+ and Dy3+, especially of Tb3+.
引用
收藏
页码：289 / 294
页数：6
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