(Benzoylacetonato-O,O')(2,2'-bipyridine-N,N')(nitrato-O)copper(II)

被引：19
|
作者：
Zhang, L [1 ]
Xu, DJ [1 ]
Xu, YZ [1 ]
Gu, JM [1 ]
机构：
[1] HANGZHOU UNIV,CENT LAB,HANGZHOU 310028,PEOPLES R CHINA
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷
关键词：
D O I：
10.1107/S0108270196012358
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Cu-II atom in the title complex, (2,2'-bipyridine-N,N')(nitrato-O)(1-phenyl-1,3-butanedionato-O,O')copper(II), [Cu(C10H9O2)(NO3)(C10H8N2)], has a square-pyramidal coordination. Both the benzoylacetone anion and the 2,2'-bipyridine ligand chelate to the Cu-II atom in the equatorial plane, while a nitrate anion occupies the apical site, with a longer Cu-O distance of 2.335 (4) Angstrom. Within the delocalized enol ring of benzoylacetone, the C-C bond closest to the phenyl ring is longer than the C-C bond farthest from the phenyl ring.
引用
收藏
页码：299 / 301
页数：3
相关论文
共 50 条
  • [1] The polymeric copper complex 2,2′-bipyridine-N,N′-(μ-maleato-O,O′:O") copper(II) dihydrate
    Zhang, CG
    Sun, J
    Kong, XF
    Zhao, CX
    JOURNAL OF COORDINATION CHEMISTRY, 2000, 49 (03) : 181 - 188
  • [2] STRUCTURE OF (NITRATO-O)(NITRATO-O,O')-TRIS(PYRIDAZINE-N)COPPER(II)
    OTIENO, T
    RETTIG, SJ
    THOMPSON, RC
    TROTTER, J
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 : 2067 - 2070
  • [3] CATENA-POLY(MU-(2,2'-BIPYRIMIDINE-N,N'-N'',N''')-[(NITRATO-O,O')COPPER(II)]-DI(MU-NITRATO-MU-O)-[(NITRATO-O,O')COPPER(II)]),[CU2(NO3)4(C8H6N4)]
    DEMUNNO, G
    BRUNO, G
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (DEC) : 2030 - 2032
  • [4] The polymeric copper(II) complex, 2,2'-bipyridine-N,N'-(mu-nicotinato-O,O':N) monoaquacopper (II) nitrate dihydrate
    Xu, DJ
    Xie, AL
    Xu, YZ
    Zhang, CG
    Chen, WG
    JOURNAL OF COORDINATION CHEMISTRY, 1996, 39 (3-4) : 273 - 280
  • [5] Bis(2-aminomethylpyridine-N,N')bis(nitrato-O)copper(II)
    Kooijman, H
    Spek, AL
    Rehorst, D
    Driessen, WL
    Reedijk, J
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 1596 - 1598
  • [6] (2,2 '-Bipyridine-kappa(2) N, N ')bis(nitrato-kappa O-2, O ')copper(II)
    Liu, Feng-Yi
    Zhang, Ming -Hui
    Kou, Jun-Feng
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M609 - +
  • [7] Bis(2-aminomethylpyridine-N,N′)bis(nitrato-O)copper(II)
    Utrecht Univ, Utrecht, Netherlands
    Acta Crystallogr Sect C Cryst Struct Commun, pt 11 (1596-1598):
  • [8] Poly[[[aqua(2,2′-bipyridine-N,N′)cadmium(II)]-μ3-sulfito-O:O:O′] hydrate]
    Harvey, M
    Baggio, S
    Baggio, R
    Pardo, H
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 1278 - 1280
  • [9] Bis(2,2′-bipyridine-κ2N,N′)(nitrato-κO)copper(II) hexafluorophosphate
    Beobide, Garikoitz
    Castillo, Oscar
    Garcia-Couceiro, Urko
    Garcia-Teran, Juan P.
    Luque, Antonio
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M1353 - M1355
  • [10] Bis(2,2′-bipyridine-κ2N,N′)(nitrato-κO)copper(II) perchlorate
    Zhu, Yu
    Wu, Yun-Long
    Huang, Chun-Xia
    Xie, Ji-Min
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M306 - U255
12345