Microstructure and ion transport in Li1+x Ti2-x M x (PO4)3 (M = Cr, Fe, Al) NASICON-type materials

被引：19
|
作者：
Svitan'ko, A. I. [1 ]
Novikova, S. A. [1 ]
Stenina, I. A. [1 ]
Skopets, V. A. [1 ]
Yaroslavtsev, A. B. [1 ]
机构：
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
来源：
INORGANIC MATERIALS | 2014年 / 50卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
SOLID ELECTROLYTES; CATION MOBILITY; CONDUCTORS; CONDUCTIVITY; PHOSPHATES; CHEMISTRY;
D O I：
10.1134/S0020168514030145
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Li1 + x Ti2 - x M (x) (PO4)(3) (M = Cr, Fe, Al) NASICON-type materials have been prepared by the Pechini process and solid-state reactions and characterized by X-ray diffraction, scanning electron microscopy, and impedance spectroscopy. We have identified the factors that determine the rate of ion transport in nanocrystalline and bulk samples at low and high temperatures. The effects of the preparation procedure and heterovalent doping on the ionic conductivity of the materials have been assessed. Heterovalent doping is shown to have a considerably stronger effect on the ionic conductivity in comparison with the microstructure of the materials.
引用
收藏
页码：273 / 279
页数：7
相关论文
共 50 条
  • [31] NASICON-type Li0.5M0.5Ti1.5Fe0.5(PO4)3 (M = Mn, Co, Mg) phosphates as electrode materials for lithium-ion batteries
    Elbouazzaoui, Kenza
    Srout, Mohammed
    Saadoune, Ismael
    Bih, Lahcen
    Ben Youcef, Hicham
    Dahbi, Mouad
    Mansori, Mohammed
    ELECTROCHIMICA ACTA, 2021, 399
  • [32] Structural evolution of NASICON-type Li1+xAlxGe2-x(PO4)3 using in situ synchrotron X-ray powder diffraction
    Safanama, Dorsasadat
    Sharma, Neeraj
    Rao, Rayavarapu Prasada
    Brand, Helen E. A.
    Adams, Stefan
    JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (20) : 7718 - 7726
  • [33] Influence of preparation temperature on ionic conductivity of titanium-defective Li1+4xTi2-x(PO4)3 NASICON-type materials
    Kahlaoui, Radhouene
    Arbi, Kamel
    Jimenez, Ricardo
    Sobrados, Isabel
    Sanz, Jesus
    Ternane, Riadh
    JOURNAL OF MATERIALS SCIENCE, 2020, 55 (20) : 8464 - 8476
  • [34] Synthesis and Conductivity Study of Solid Electrolytes Li1+x Al x Ge2-x (PO4)3 (x=0-0.65)
    Moshareva, M. A.
    Novikova, S. A.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2018, 63 (03) : 319 - 323
  • [35] Electrical and mechanical properties of water-stable NASICON-type Li1+xAlxGe0.2Ti1.8-x(PO4)3
    Bai, Fan
    Mori, Daisuke
    Taminato, Sou
    Takeda, Yasuo
    Yamamoto, Osamu
    Nemori, Hiroyoshi
    Nomura, Masaya
    Imanishi, Nobuyuki
    SOLID STATE IONICS, 2020, 345
  • [36] Influence of preparation temperature on ionic conductivity of titanium-defective Li1+4xTi2−x(PO4)3 NASICON-type materials
    Radhouene Kahlaoui
    Kamel Arbi
    Ricardo Jimenez
    Isabel Sobrados
    Jesus Sanz
    Riadh Ternane
    Journal of Materials Science, 2020, 55 : 8464 - 8476
  • [37] Characterization of Nasicon-type Li3Fe2-2xTixMnx(PO4)3/C cathode materials
    Sun, Jun-Kang
    Huang, Fu-Qiang
    Wang, Yao-Ming
    Shan, Zhi-Chao
    Liu, Zhan-Qiang
    Liu, Min-Ling
    Xia, Yu-Juan
    Li, Kai-Qiang
    JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 469 (1-2) : 327 - 331
  • [38] Synthesis and ionic conductivity of (NH4)1–xHxHf2(PO4)3 (x = 0–1) NASICON-type materials
    M. A. Moshareva
    S. A. Novikova
    A. B. Yaroslavtsev
    Inorganic Materials, 2016, 52 : 1283 - 1290
  • [39] Study of the glass-to-crystal transformation of the NASICON-type solid electrolyte Li1+xAlxGe2 - x(PO4)3
    Liu, Zhongqing
    Venkatachalam, Sabarinathan
    Kirchhain, Holger
    van Wuellen, Leo
    SOLID STATE IONICS, 2016, 295 : 32 - 40
  • [40] Distribution and mobility of lithium in NASICON-type Li1-xTi2-xNbx(PO4)3 (0 ≤ x ≤ 0.5) compounds
    Kahlaoui, Radhouene
    Arbi, Kamel
    Jimenez, Ricardo
    Sobrados, Isabel
    Sanz, Jesus
    Ternane, Riadh
    MATERIALS RESEARCH BULLETIN, 2018, 101 : 146 - 154
12345