Solvent effect on the volume of the Diels-Alder reaction between tetracyanoethylene and trans,trans-1,4-diphenyl-1,3-butadiene

被引：0
|
作者：
Kiselev, VD [1 ]
Medvedeva, MD [1 ]
Kashaeva, EA [1 ]
Shikhaab, MS [1 ]
Iskhakova, GG [1 ]
Konovalov, AI [1 ]
机构：
[1] Kazan VI Lenin State Univ, AM Butlerov Chem Res Inst, Kazan 420008, Tatarstan, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2002年 / 72卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1023/A:1015456003857
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
From the partial molar volumes of tetracyanoethylene, trans,trans-1,4-diphenyl-1,3-butadiene, and their Diels-Alder adduct, the volumes of the reaction in a series of solvents at 25degreesC (cm(3) mol(-1)) were calculated: in dioxane, -26.4; in chloroform, -34.9; in ethyl acetate, -34.5; in acetonitrile, -4.4; in cyclohexanone, -34.0; in 1,2-dichloroethane, -31.8; in benzene, -26.9; in toluene, -24.5; in o-xylene, -21.1; and in mesitylene, -16.9. The solvent effects on the activation and reaction volumes and on the partial molar volumes of the reactants, activated complex, and adduct were discussed.
引用
收藏
页码：432 / 435
页数：4
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