Solvent effect on the volume of the Diels-Alder reaction between tetracyanoethylene and trans,trans-1,4-diphenyl-1,3-butadiene

被引：0

作者：

Kiselev, VD ^{[1
]}

Medvedeva, MD ^{[1
]}

Kashaeva, EA ^{[1
]}

Shikhaab, MS ^{[1
]}

Iskhakova, GG ^{[1
]}

Konovalov, AI ^{[1
]}

机构：

[1] Kazan VI Lenin State Univ, AM Butlerov Chem Res Inst, Kazan 420008, Tatarstan, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2002年 / 72卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1023/A:1015456003857

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

From the partial molar volumes of tetracyanoethylene, trans,trans-1,4-diphenyl-1,3-butadiene, and their Diels-Alder adduct, the volumes of the reaction in a series of solvents at 25degreesC (cm(3) mol(-1)) were calculated: in dioxane, -26.4; in chloroform, -34.9; in ethyl acetate, -34.5; in acetonitrile, -4.4; in cyclohexanone, -34.0; in 1,2-dichloroethane, -31.8; in benzene, -26.9; in toluene, -24.5; in o-xylene, -21.1; and in mesitylene, -16.9. The solvent effects on the activation and reaction volumes and on the partial molar volumes of the reactants, activated complex, and adduct were discussed.

引用

页码：432 / 435

页数：4

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