Recent advances in ruthenium-based olefin metathesis

被引:499
|
作者
Ogba, O. M. [1 ]
Warner, N. C. [1 ]
O'Leary, D. J. [1 ]
Grubbs, R. H. [2 ]
机构
[1] Pomona Coll, Dept Chem, 645 North Coll Ave, Claremont, CA 91775 USA
[2] CALTECH, Div Chem & Chem Engn, 1200 E Calif Blvd, Pasadena, CA 91125 USA
基金
美国国家科学基金会;
关键词
RING-CLOSING METATHESIS; SELECTIVE CROSS-METATHESIS; BRUSH BLOCK-COPOLYMERS; TOTAL ANALYSIS SYSTEMS; ONE-POT SYNTHESIS; OPENING METATHESIS; KINETIC SELECTIVITY; POLY(VINYL ALCOHOL); EFFICIENT SYNTHESIS; MOLECULAR MECCANO;
D O I
10.1039/c8cs00027a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ruthenium-based olefin metathesis catalysts, known for their functional group tolerance and broad applicability in organic synthesis and polymer science, continue to evolve as an enabling technology in these areas. A discussion of recent mechanistic investigations is followed by an overview of selected applications.
引用
收藏
页码:4510 / 4544
页数:35
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