Recent advances in ruthenium-based olefin metathesis

被引:499
|
作者
Ogba, O. M. [1 ]
Warner, N. C. [1 ]
O'Leary, D. J. [1 ]
Grubbs, R. H. [2 ]
机构
[1] Pomona Coll, Dept Chem, 645 North Coll Ave, Claremont, CA 91775 USA
[2] CALTECH, Div Chem & Chem Engn, 1200 E Calif Blvd, Pasadena, CA 91125 USA
基金
美国国家科学基金会;
关键词
RING-CLOSING METATHESIS; SELECTIVE CROSS-METATHESIS; BRUSH BLOCK-COPOLYMERS; TOTAL ANALYSIS SYSTEMS; ONE-POT SYNTHESIS; OPENING METATHESIS; KINETIC SELECTIVITY; POLY(VINYL ALCOHOL); EFFICIENT SYNTHESIS; MOLECULAR MECCANO;
D O I
10.1039/c8cs00027a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ruthenium-based olefin metathesis catalysts, known for their functional group tolerance and broad applicability in organic synthesis and polymer science, continue to evolve as an enabling technology in these areas. A discussion of recent mechanistic investigations is followed by an overview of selected applications.
引用
收藏
页码:4510 / 4544
页数:35
相关论文
共 50 条
  • [21] Using stereoretention for the synthesis of E-macrocycles with ruthenium-based olefin metathesis catalysts
    Ahmed, Tonia S.
    Montgomery, T. Patrick
    Grubbs, Robert H.
    [J]. CHEMICAL SCIENCE, 2018, 9 (14) : 3580 - 3583
  • [22] Metal-centered oxidations facilitate the removal of ruthenium-based olefin metathesis catalysts
    Rosen, Evelyn L.
    Varnado, C. Daniel, Jr.
    Arumugam, Kuppuswamy
    Bielawski, Christopher W.
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2013, 745 : 201 - 205
  • [23] Recoverable ruthenium-based olefin metathesis catalysts via host-guest complexation
    Chung, Hoyong
    Ondrusek, Brian A.
    Kim, Cheoljae
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [24] Recent advances in olefin metathesis chemistry
    Schrock, Richard R.
    [J]. CHIMICA OGGI-CHEMISTRY TODAY, 2009, 27 (03) : 2 - 5
  • [25] Ruthenium-Based Olefin Metathesis Catalysts Bearing N-Heterocyclic Carbene Ligands
    Samojlowicz, Cezary
    Bieniek, Michal
    Grela, Karol
    [J]. CHEMICAL REVIEWS, 2009, 109 (08) : 3708 - 3742
  • [26] SYNTHESES AND ACTIVITIES OF NEW SINGLE-COMPONENT, RUTHENIUM-BASED OLEFIN METATHESIS CATALYSTS
    NGUYEN, ST
    GRUBBS, RH
    ZILLER, JW
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (21) : 9858 - 9859
  • [27] New Concepts in Designing Ruthenium-Based Second Generation Olefin Metathesis Catalysts and Their Application
    Kadyrov, Renat
    Rosiak, Anna
    Tarabocchia, John
    Szadkowska, Anna
    Bieniek, Michal
    Grela, Karol
    [J]. CATALYSIS OF ORGANIC REACTIONS, 2009, 123 : 217 - +
  • [28] Recent advances in ruthenium-based electrocatalysts for the hydrogen evolution reaction
    Bae, Seo-Yoon
    Mahmood, Javeed
    Jeon, In-Yup
    Baek, Jong-Beom
    [J]. NANOSCALE HORIZONS, 2020, 5 (01) : 43 - 56
  • [29] Novel η3-vinylcarbene complexes derived from ruthenium-based olefin metathesis catalysts
    Trnka, TM
    Day, MW
    Grubbs, RH
    [J]. ORGANOMETALLICS, 2001, 20 (18) : 3845 - 3847
  • [30] High Trans Kinetic Selectivity in Ruthenium-Based Olefin Cross-Metathesis through Stereoretention
    Johns, Adam M.
    Ahmed, Tonia S.
    Jackson, Bradford W.
    Grubbs, Robert H.
    Pederson, Richard L.
    [J]. ORGANIC LETTERS, 2016, 18 (04) : 772 - 775