A highly active chiral ruthenium-based catalyst for enantioselective olefin metathesis

被引：64
|
作者：
Fournier, Pierre-Andre [1 ]
Collins, Shawn K. [1 ]
机构：
[1] Univ Montreal, Dept Chem, Montreal, PQ H3C 3J7, Canada
来源：
ORGANOMETALLICS | 2007年 / 26卷 / 12期
关键词：
D O I：
10.1021/om700312c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A chiral Ru-based olefin metathesis catalyst bearing a chiral NHC ligand that is both C-1-symmetric and monodentate is described. The catalyst shows increased reactivity in comparison to existing chiral Ru-based catalysts that possess a C-2-symmetric NHC and successfully induces asymmetry in desymmetrization reactions.
引用
收藏
页码：2945 / 2949
页数：5
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