BIO-BASED EPOXY RESINS AND COMPOSITES FROM EPDXIDIZED LINSEED OIL CROSSLINKED WITH DIFFERENT CYCLIC ANHYDRIDES AND THEIR COMBINATION WITH LIGNIN

被引：13
|
作者：
Dinu, Roxana [1 ]
Mija, Alice [1 ]
机构：
[1] Univ Cote dAzur, Inst Chim Nice, UMR CNRS 7272, 28 Av Valrose, F-06108 Nice 02, France
来源：
CELLULOSE CHEMISTRY AND TECHNOLOGY | 2020年 / 54卷 / 9-10期
基金：
欧盟地平线“2020”;
关键词：
FIBER; WATER; LIGNOCELLULOSE; THERMOSETS; POLYMERS; ETHANOL; IMPACT;
D O I：
10.35812/CelluloseChemTechnol.2020.54.89
中图分类号：
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号：
0805 ; 080502 ; 0822 ;
摘要：
Biobased resins and composites with high biobased carbon content were prepared and characterized. Epoxidized linseed oil (ELO) was copolymerized with four cyclic anhydrides, the initiation step being optimized in terms of initiator nature and its ratio. The optimized ELO/anhydride formulations were combined with a high load of lignin, as biofiller, similar to 30 wt%. The obtained materials were characterized by TGA, DSC, DMA, gel content, water absorption (WA) and Shore hardness tests. The results revealed very good thermomechanical properties, high gel content and low WA, opening the way to their utilization as a sustainable alternative to oil-based resins and composites.
引用
收藏
页码：925 / 938
页数：14
相关论文
共 50 条
  • [21] Development of toughened bio-based epoxy with epoxidized linseed oil as reactive diluent and cured with bio-renewable crosslinker
    Sahoo, Sushanta K.
    Khandelwal, Vinay
    Manik, Gaurav
    [J]. POLYMERS FOR ADVANCED TECHNOLOGIES, 2018, 29 (01) : 565 - 574
  • [22] Bio-based thermosets from the free radical polymerization of conjugated linseed oil
    Henna, PH
    Larock, RC
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U3717 - U3718
  • [23] Development of completely bio-based epoxy networks derived from epoxidized linseed and castor oil cured with citric acid
    Sahoo, Sushanta K.
    Khandelwal, Vinay
    Manik, Gaurav
    [J]. POLYMERS FOR ADVANCED TECHNOLOGIES, 2018, 29 (07) : 2080 - 2090
  • [24] Preparation of degradable bio-based silicone/epoxy hybrid resins towards low dielectric composites
    Zhang, Pengbo
    Long, Jun
    Xue, Kangle
    Liu, Hailong
    Song, ZiDie
    Liu, Ming
    Yao, Tongjie
    Liu, Li
    [J]. EUROPEAN POLYMER JOURNAL, 2022, 181
  • [25] Synthesis and Characterization of Bio-based Epoxy Resins Derived from Vanillyl Alcohol
    Hernandez, Eric D.
    Bassett, Alexander W.
    Sadler, Joshua M.
    La Scala, John J.
    Stanzione, Joseph F., III
    [J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2016, 4 (08): : 4328 - 4339
  • [26] Bio-Based Epoxy Resins Derived From Eugenol With Low Dielectric Constant
    Liu, Yuan
    Dai, Jinyue
    Liu, Xiaoqing
    Luo, Jun
    You, Shusen
    Zhu, Jin
    Ma, Songqi
    Jia, Zhen
    [J]. JOURNAL OF ELECTRONIC PACKAGING, 2017, 139 (03)
  • [27] Bio-based coatings from epoxy resins crosslinked with a rosin acid derivative for wood thermal and anti-fungal protection
    Rosu, Liliana
    Mustata, Fanica
    Rosu, Dan
    Varganici, Cristian-Dragos
    Rosca, Irina
    Rusu, Teodora
    [J]. PROGRESS IN ORGANIC COATINGS, 2021, 151
  • [28] Synthesis and chemoselective crosslinking of functionalized polyesters from bio-based epoxides and cyclic anhydrides
    Haslewood, Marcell N. D.
    Farmer, Thomas J.
    North, Michael
    [J]. JOURNAL OF POLYMER SCIENCE, 2023, 61 (04) : 311 - 322
  • [29] Bio-based carbon nanotube composites from tung oil
    Bice, Scott K.
    Beckler, Brenda
    Quirino, Rafael L.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [30] New bio-based epoxy materials and foams from microalgal oil
    Negrell, Claire
    Cornille, Adrien
    Nascimento, Patricia de Andrade
    Robin, Jean-Jacques
    Caillol, Sylvain
    [J]. EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, 2017, 119 (04)
12345