Bio-Based Epoxy Resins Derived From Eugenol With Low Dielectric Constant

被引：30
|
作者：
Liu, Yuan [1 ,2 ,3 ]
Dai, Jinyue [1 ,3 ]
Liu, Xiaoqing [1 ,3 ,4 ]
Luo, Jun [2 ]
You, Shusen [1 ,3 ,4 ,5 ]
Zhu, Jin [4 ,5 ]
Ma, Songqi [4 ,5 ]
Jia, Zhen [6 ,7 ]
机构：
[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Polymer & Composites Div, Ningbo 315201, Zhejiang, Peoples R China
[2] Guiyang Univ, Engn Res Ctr Mat Protect Wear & Corros Guizhou Pr, Guiyang 550005, Guizhou, Peoples R China
[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[4] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Polymer & Composites Div, Ningbo 315201, Peoples R China
[5] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[6] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China
[7] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
JOURNAL OF ELECTRONIC PACKAGING | 2017年 / 139卷 / 03期
基金：
中国国家自然科学基金;
关键词：
eugenol; biomass; bio-based epoxy resin; low dielectric constant; ELECTRONIC PACKAGING APPLICATIONS; COMPOSITES; LIGNIN; PERFORMANCE; SILOXANE; ADHESIVE; BEHAVIOR; MICRO;
D O I：
10.1115/1.4036818
中图分类号：
TM [电工技术]; TN [电子技术、通信技术];
学科分类号：
0808 ; 0809 ;
摘要：
In this paper, a series of bio-based epoxy resins containing organic silicone were prepared from eugenol through a mild synthetic route. Then, 4,4'-diaminophenyl methane (DDM) was applied to cure these epoxy resins, and bisphenol A epoxy resin (DGEBA) was used as a control. The chemical structures of the synthesized resins were characterized by nuclear magnetic resonance (H-1-NMR). Properties of the cured epoxy resins were investigated by dielectric test, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA), and scanning electron microscopy (SEM). Compared with DGEBA, the bio-based epoxy resin containing cyclic organic silicon structure exhibited a dramatically lower dielectric constant at both low and high frequencies (3.46, 1 kHz, room temperature). Moreover, the silicone-modified bio-based epoxy resins demonstrated no weight loss below 325 degrees C and higher residues at 800 degrees C than that of DGEBA.
引用
收藏
页数：7
相关论文
共 50 条
  • [1] Novel bio-based epoxy resins from eugenol derived copolymers as an alternative to DGEBA resin
    Kalita, Deep J.
    Tarnavchyk, Ihor
    Kalita, Harjyoti
    Chisholm, Bret J.
    Webster, Dean C.
    PROGRESS IN ORGANIC COATINGS, 2023, 178
  • [2] Bio-Based Epoxy Resins Derived from Eugenol with High Glass Transition Temperatures as Substitutes for DGEBA
    Schamel, Elisabeth
    Bauer, Florian
    Schlachter, Herbert
    Wehnert, Gerd
    Soethje, Dominik
    MACROMOLECULAR MATERIALS AND ENGINEERING, 2025,
  • [3] Low dielectric constant polymers derived from bio-based anethole and isoeugenol
    Li, Minghui
    Sun, Jing
    Fang, Qiang
    EUROPEAN POLYMER JOURNAL, 2024, 202
  • [4] A fluoropolymer with a low dielectric constant at a high frequency derived from bio-based anethole
    Li, Minghui
    Sun, Jing
    Fang, Qiang
    POLYMER CHEMISTRY, 2021, 12 (31) : 4501 - 4507
  • [5] A Bio-Based Allylphenol (Eugenol)-Functionalized Fluorinated Maleimide with Low Dielectric Constant and Low Water Uptake
    Fang, Linxuan
    Zhou, Junfeng
    Wang, Jiajia
    Sun, Jing
    Fang, Qiang
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2018, 219 (20)
  • [6] Synthesis and Characterization of Bio-based Epoxy Resins Derived from Vanillyl Alcohol
    Hernandez, Eric D.
    Bassett, Alexander W.
    Sadler, Joshua M.
    La Scala, John J.
    Stanzione, Joseph F., III
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2016, 4 (08): : 4328 - 4339
  • [7] Green preparation of robust hydrophobic bio-based epoxy resin with low dielectric constant
    Fu, Fei
    Shen, Minggui
    Wang, Dan
    Liu, He
    Xu, Xu
    Shang, Shibin
    Song, Zhanqian
    Song, Jie
    INDUSTRIAL CROPS AND PRODUCTS, 2022, 188
  • [8] Novel bio-based epoxy resins from eugenol as an alternative to BPA epoxy and high throughput screening of the cured coatings
    Kalita, Deep J.
    Tarnavchyk, Ihor
    Chisholm, Bret J.
    Webster, Dean C.
    POLYMER, 2021, 233
  • [9] Novel bio-based epoxy resins
    Alam, Samim
    Fernando, Shashi
    Jayasooriyamu, Anurad
    Chisholm, Brett
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [10] Preparation of degradable bio-based silicone/epoxy hybrid resins towards low dielectric composites
    Zhang, Pengbo
    Long, Jun
    Xue, Kangle
    Liu, Hailong
    Song, ZiDie
    Liu, Ming
    Yao, Tongjie
    Liu, Li
    EUROPEAN POLYMER JOURNAL, 2022, 181
12345