Enantiospecific first total synthesis of (+)-trans-α-himachalene

被引:13
|
作者
Srikrishna, A [1 ]
Kumar, PR [1 ]
机构
[1] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India
关键词
terpene synthesis; pheromones; carbonyl ene reaction;
D O I
10.1016/j.tetlet.2004.07.103
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An enantiospecific first total synthesis of (+)-trans-alpha-himachalene, one of the eight male specific sesquiterpenes isolated from the crucifer flea beetle Phyllotreta cruciferae, starting from the readily and abundantly available monoterpene, (R)-carvone, is described. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:6867 / 6870
页数:4
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