Synthesis, structure and properties of a novel 3D pentanuclear [Zn5(OH)2]8+ cluster-based (3,4,11)-connected coordination polymer

被引：3

作者：

Kan, Wei-Qiu ^{[1
]}

Wen, Shi-Zheng ^{[1
,2
]}

Kan, Yu-He ^{[1
]}

Hu, Hua-You ^{[1
]}

Yang, Lin ^{[1
]}

Li, Dan ^{[1
]}

机构：

[1] Huaiyin Normal Univ, Sch Chem & Chem Engn, Jiangsu Prov Key Lab Chem Low Dimens Mat, Huaian 223300, Peoples R China

[2] Huaiyin Normal Univ, Huaian Key Lab Funct Mat Informat, Sch Phys & Elect Elect Engn, Huaian 223300, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 61卷

基金：

美国国家科学基金会;

关键词：

Pentanuclear cluster; Highly connected; Coordination polymer; Optical band gap; Photoluminescence; METAL-ORGANIC FRAMEWORKS; 2ND-ORDER NONLINEAR OPTICS; PHOTOLUMINESCENT PROPERTIES; LIGAND; SERIES; PHOTOCATALYSIS; LUMINESCENCE; LINKER;

D O I：

10.1016/j.inoche.2015.08.026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel coordination polymer based on the multidentate N-donor ligand 14(1H-1,2,4-triazol-1-yOmethyl)-3,5-bis(3-pyridy1)-1,2,4-triazole (3,3'-tmbpt) and 1,2,4,5-benzenetetracarboxylate anion (btec), namely, [Zn-5(3,3'-tmbpt)(btec)(2)(OH)(2)] (1), has been synthesized hydrothermally. Compound 1 displays a rare 3D (3,4,11)-connected framework based on a [Zn-5(OH)(2)](8+) cluster. The optical band gap and photoluminescent property of compound 1 have been studied. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：85 / 88

页数：4

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