Synthesis, Structure, Luminescence and Thermal Stability Properties of a New(3,4)-Connected 2D Zn Coordination Polymer

被引：2

作者：

王海鹏 ^{[1
]}

王宏亮 ^{[2
]}

李宝龙 ^{[3
]}

机构：

[1] School of Chemistry and Environmental Engineering, Shanxi Datong University

[2] Institute of Materials Science&Department of Chemistry, Xinzhou Teachers University

[3] State and Local Joint Engineering Laboratory for Functional Polymeric Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University

来源：

Chinese Journal of Structural Chemistry | 2020年 / 39卷 / 10期

关键词：

D O I：

10.14102/j.cnki.0254-5861.2011-2708

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

070304 ; 081704 ;

摘要：

A new zinc coordination polymer {[Zn;（ttmb）;（dca）;（H;O）].H;O};（1.H;O） was synthesized by the reaction of 1,3,5-tris（1,2,4-triazol-1-ylmethyl）benzene（ttmb）, Zn（Ⅱ） salt and sodium dicyanamide(Na（dca）). The structure of the title compound was determined by single-crystal X-ray diffraction, elemental analyses and IR spectra. 1 exhibits a（3,4）-connected 2D double-layer network with the point symbol of {63}{(66}. The solid-state luminescence shows a strong emission band at 485 nm upon excitation at 384 nm. The thermal stability properties were also studied.

引用

页码：1835 / 1840

页数：6

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