Synthesis and characterization of a novel lanthanide coordination polymer with network structure based on [Er4(μ3-OH)4]8+ cluster and 2,2'-bipyridine-3,3'-dicarboxylate

被引：30

作者：

Hu, Ming

Wang, Qing-Lun

Xu, Gong-Feng

Zhao, Bin

Deng, Gui-Ru

Zhang, Yan-Hong

Yang, Guang-Ming ^{[1
]}

机构：

[1] Nankai Univ, Coll Chem, Tianjin 300071, Peoples R China

[2] InnerMongolia Univ, Coll Chem, Hohhot 010021, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2007年 / 10卷 / 10期

基金：

中国国家自然科学基金;

关键词：

lanthanide; coordination polymers; cluster compounds; x-ray diffraction; hydrothermal synthesis;

D O I：

10.1016/j.inoche.2007.04.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel Coordination polymer, [{Er-4(mu(3)-OH)(4) (bpdc)(4)(H2O)}(2)] (H2O)(16.5) (1) was obtained by hydrothermal reaction. The cubane-like [Er-4(mu(3)-OH)(4)](8+) as building block, it was further assembled into two-dimensional network structure through the linkage of 2,2'-bipyridine-3,3'-dicarboxylate (bpdc) with four different coordination modes. The magnetic property of the compound was discussed further. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：1177 / 1180

页数：4

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