Metal-organic frameworks containing N-heterocyclic carbenes and their precursors

被引：104

作者：

Ezugwu, Chizoba I. ^{[1
,2
]}

Kabir, Nawsad Alam ^{[1
,2
]}

Yusubov, Mekhman ^{[3
]}

Verpoort, Francis ^{[1
,2
,3
,4
]}

机构：

[1] Wuhan Univ Technol, Ctr Chem & Mat Engn, State Key Lab Adv Technol Mat Synth & Proc, Lab Organometall Catalysis & Ordered Mat, Wuhan 430070, Peoples R China

[2] Wuhan Univ Technol, Fac Sci, Dept Appl Chem, Wuhan 430070, Peoples R China

[3] Natl Res Tomsk Polytech Univ, Tomsk 634050, Russia

[4] Univ Ghent, Inchon, South Korea

来源：

COORDINATION CHEMISTRY REVIEWS | 2016年 / 307卷

基金：

美国国家科学基金会;

关键词：

MOFs; NHC precursors; Azolium-containing ligands; Postsynthetic modification; OLEFIN METATHESIS CATALYSTS; SUZUKI-MIYAURA; ELECTRONIC-PROPERTIES; IMIDAZOLIUM DICARBOXYLATE; ORGANOMETALLIC CHEMISTRY; HETEROGENEOUS CATALYSIS; COORDINATION NETWORKS; NUCLEOPHILIC CARBENES; COMPLEXES SYNTHESIS; BUCHWALD-HARTWIG;

D O I：

10.1016/j.ccr.2015.06.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metal-organic frameworks (MOFs) are coordination networks formed by self-assembly of metal ions or clusters and organic linkers. The functionalities and versatilities of MOF materials are enhanced by designing the frameworks with linkers, which have extra active functional groups that can be modified presynthetically, in situ, or postsynthetically. The carbenic carbon in N-heterocyclic carbenes enhances the potential of MOFs synthesized from azolium-containing linkers. In this review, we provide a survey and discussion of N-heterocyclic carbene precursor-containing MOFs and their various applications. This review will guide researchers and synthetic chemists attempting to design MOFs from N-heterocyclic carbene precursors. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：188 / 210

页数：23

共 50 条

[31] Synthesis and Applications of Heteromultimetallic Complexes Containing N-Heterocyclic Carbenes
Gu Shaojin
Xu Weilin
Huang Jingjing
PROGRESS IN CHEMISTRY, 2013, 25 (2-3) : 330 - 339
[32] N-Heterocyclic carbenes:: Effective organic catalysts for living polymerization
Dove, Andrew P.
Pratt, Russell C.
Lohmeijer, Bas G. G.
Culkin, Darcy A.
Hagberg, Eric C.
Nyce, Gregory W.
Waymouth, Robert M.
Hedrick, James L.
POLYMER, 2006, 47 (11) : 4018 - 4025
[33] Interactions between N-heterocyclic carbenes and organic acids.
Davidson, MG
Cowan, JA
Clyburne, JAC
Howard, JAK
Küpper, P
Leech, MA
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 222 : U621 - U621
[34] Stable Organic Radicals Derived from N-Heterocyclic Carbenes
Kim, Youngsuk
Lee, Eunsung
CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (72) : 19110 - 19121
[35] Group 7 transition metal complexes with N-heterocyclic carbenes
Hock, Sebastian J.
Schaper, Lars-Arne
Herrmann, Wolfgang A.
Kuehn, Fritz E.
CHEMICAL SOCIETY REVIEWS, 2013, 42 (12) : 5073 - 5089
[36] Theoretical NMR spectroscopy of N-heterocyclic carbenes and their metal complexes
Falivene, Laura
Cavallo, Luigi
COORDINATION CHEMISTRY REVIEWS, 2017, 344 : 101 - 114
[37] N-heterocyclic carbenes as bridgehead donors in metal pincer complexes
He, Fengkai
Zois, Konstantinos P.
Tzeli, Demeter
Danopoulos, Andreas A.
Braunstein, Pierre
COORDINATION CHEMISTRY REVIEWS, 2024, 514
[38] New annulated N-heterocyclic carbenes and their transition metal complexes
Bettler, Graeme
Changas, Angelo
Buckner, Ossie
Boudreaux, Chance
Norvell, Bradley
Tapu, Daniela
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
[39] N-Heterocyclic carbenes as tunable ligands for catalytic metal surfaces
Maximilian Koy
Peter Bellotti
Mowpriya Das
Frank Glorius
Nature Catalysis, 2021, 4 : 352 - 363
[40] N-Heterocyclic carbenes as tunable ligands for catalytic metal surfaces
Koy, Maximilian
Bellotti, Peter
Das, Mowpriya
Glorius, Frank
NATURE CATALYSIS, 2021, 4 (05) : 352 - 363

← 1 2 3 4 5 →