Metal-organic frameworks containing N-heterocyclic carbenes and their precursors

被引：104

作者：

Ezugwu, Chizoba I. ^{[1
,2
]}

Kabir, Nawsad Alam ^{[1
,2
]}

Yusubov, Mekhman ^{[3
]}

Verpoort, Francis ^{[1
,2
,3
,4
]}

机构：

[1] Wuhan Univ Technol, Ctr Chem & Mat Engn, State Key Lab Adv Technol Mat Synth & Proc, Lab Organometall Catalysis & Ordered Mat, Wuhan 430070, Peoples R China

[2] Wuhan Univ Technol, Fac Sci, Dept Appl Chem, Wuhan 430070, Peoples R China

[3] Natl Res Tomsk Polytech Univ, Tomsk 634050, Russia

[4] Univ Ghent, Inchon, South Korea

来源：

COORDINATION CHEMISTRY REVIEWS | 2016年 / 307卷

基金：

美国国家科学基金会;

关键词：

MOFs; NHC precursors; Azolium-containing ligands; Postsynthetic modification; OLEFIN METATHESIS CATALYSTS; SUZUKI-MIYAURA; ELECTRONIC-PROPERTIES; IMIDAZOLIUM DICARBOXYLATE; ORGANOMETALLIC CHEMISTRY; HETEROGENEOUS CATALYSIS; COORDINATION NETWORKS; NUCLEOPHILIC CARBENES; COMPLEXES SYNTHESIS; BUCHWALD-HARTWIG;

D O I：

10.1016/j.ccr.2015.06.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metal-organic frameworks (MOFs) are coordination networks formed by self-assembly of metal ions or clusters and organic linkers. The functionalities and versatilities of MOF materials are enhanced by designing the frameworks with linkers, which have extra active functional groups that can be modified presynthetically, in situ, or postsynthetically. The carbenic carbon in N-heterocyclic carbenes enhances the potential of MOFs synthesized from azolium-containing linkers. In this review, we provide a survey and discussion of N-heterocyclic carbene precursor-containing MOFs and their various applications. This review will guide researchers and synthetic chemists attempting to design MOFs from N-heterocyclic carbene precursors. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：188 / 210

页数：23

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