Ambient temperature proton conducting plastic crystal electrolytes

被引:40
|
作者
Abu-Lebdeh, Y [1 ]
Abouimrane, A [1 ]
Alarco, PJ [1 ]
Hammami, A [1 ]
Ionescu-Vasii, L [1 ]
Armand, M [1 ]
机构
[1] Univ Montreal, Dept Chem, Int Lab Electroact Mat, Montreal, PQ H3C 3J7, Canada
关键词
plastic crystals; protonic conductor; fuel cell; solid electrolytes;
D O I
10.1016/j.elecom.2004.02.015
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A non-aqueous ionic liquid based on imidazole was prepared and showed high proton conductivity. Its incorporation into the plastic crystal phase of succinonitrile at low, molar proportions resulted in a solid material with high conductivity throughout the plastic crystal range and of particular interest at 25 degreesC (1.5 x 10(-3) S/cm). The addition of a compatible polymer have resulted in a remarkable increase in the mechanical properties but diminished the conductivity by a one-and-a half order of magnitude. (C) 2004 Published by Elsevier B.V.
引用
收藏
页码:432 / 434
页数:3
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