The photoluminescence from (Eu, Yb) co-doped silicon-rich Si oxides

被引：2

作者：

Heng, Chenglin ^{[1
,2
]}

Su, Wenyong ^{[1
,2
]}

Zhang, Qiwei ^{[1
,2
]}

Ren, Xiaoqian ^{[3
]}

Yin, Penggan ^{[3
]}

Pan, Huiping ^{[4
]}

Yao, Shude ^{[4
]}

Finstad, Terje G. ^{[5
]}

机构：

[1] Beijing Inst Technol, Minist Educ, Key Lab Cluster Sci, Beijing 100081, Peoples R China

[2] Beijing Inst Technol, Sch Phys, Beijing 100081, Peoples R China

[3] Beihang Univ, Sch Chem & Environm, Minist Educ, Key Lab Bioinspired Smart Interfacial Sci & Techn, Beijing 100191, Peoples R China

[4] Peking Univ, Sch Phys, Beijing 100871, Peoples R China

[5] Univ Oslo, Dept Phys, N-0316 Oslo, Norway

来源：

JOURNAL OF LUMINESCENCE | 2014年 / 154卷

关键词：

Silicon rich oxide; Luminescence; Eu; Yb; Rare earth compounds; Energy transfer; SOLAR-CELLS; LUMINESCENCE; GLASSES;

D O I：

10.1016/j.jlumin.2014.04.035

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

We report on photoluminescence (PL) properties of europium (Eu) and ytterbium (Yb) co-doped siliconrich oxide films with different Si excess and after various annealings. The dominating PL signal of Eu changed gradually from that of Eu3+ ions to Eu2+ by raising the annealing temperature from 700 to 1200 degrees C. Transmission electron microscopy revealed that amorphous Eu, Yb, Si, O containing precipitates have been formed in the Si-rich oxide during 1000-1200 degrees C annealing and these precipitates are considered to be responsible for the Eu2+-related luminescence. The variation of PL intensity from Yb3+ ions with annealing in N-2, was correlated with the PL intensity from Eu. The PL of films can be altered considerably by oxidizing at different temperatures, which is discussed in terms of defects in the host oxide and excitation energy transfer. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：339 / 344

页数：6

共 50 条

[21] Preparation and photoluminescence properties of Eu3+, Y3+ co-doped Si nanowires
Yang, R. C.
Fan, Z. D.
Geng, X. P.
Wang, G. L.
Wang, F.
OPTOELECTRONICS AND ADVANCED MATERIALS-RAPID COMMUNICATIONS, 2022, 16 (1-2): : 74 - 78
[22] Er3+ photoluminescence from Er-doped silicon-rich silicon oxide films deposited by laser ablation of a Si:Er target in an oxygen atmosphere
Ha, JS
Jang, YR
Yoo, KH
Bae, CH
Nam, SH
Jeon, JS
Park, SM
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2004, 43 (4A): : 1541 - 1544
[23] Photoluminescence from Erbium-implanted silicon-rich SiO2
Lei, HB
Yang, QQ
Zhu, JL
Gao, JH
Wang, HJ
Wang, QM
CHINESE PHYSICS LETTERS, 1998, 15 (01): : 72 - 73
[24] Synthesis and photoluminescence of Y,Eu co-doped ZnO red phosphor
Lakshmanan, Arunachalam
Sivakumar, V.
Kumar, R. Satheesh
Bhaskar, R.
Jose, M. T.
Lakshminarayan, N.
MATERIALS RESEARCH BULLETIN, 2012, 47 (02) : 419 - 424
[25] Comparing models for the growth of silicon-rich oxides (SRO)
Dundar, G
Rose, K
IEEE TRANSACTIONS ON SEMICONDUCTOR MANUFACTURING, 1996, 9 (01) : 74 - 81
[26] On the Absorption and Photoluminescence Properties of Pure ZnSe and Co-Doped ZnSe:Eu3+/Yb3+ Crystals
Abbasgholi-NA, Behnaz
Aldaghri, Osamah A.
Ibnouf, Khalid Hassan
Madkhali, Nawal
Cabrera, Humberto
APPLIED SCIENCES-BASEL, 2022, 12 (09):
[27] Electroluminescence from Er and Yb co-doped silicon dioxide layers: The excitation mechanism
Prucnal, S.
Rebohle, L.
Skorupa, W.
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2011, 357 (03) : 915 - 918
[28] Photoluminescence of Er-doped silicon-rich oxide thin films with high Al concentrations
Rozo, Carlos
Fonseca, Luis F.
Jaque, Daniel
Garcia Sole, Jose
SELECTED PAPERS FROM 17TH INTERNATIONAL CONFERENCE ON DYNAMICAL PROCESSES IN EXCITED STATES OF SOLIDS (DPC'10), 2011, 13
[29] Photoluminescence, infrared, and Raman spectra of co-doped Si nanoparticles from first principles
Somogyi, Balint
Bruyer, Emilie
Gali, Adam
JOURNAL OF CHEMICAL PHYSICS, 2018, 149 (15):
[30] Energy transfer in Er:Eu:Yb co-doped tellurite glasses: Yb as enhancer and quencher
Dwivedi, Y.
Rai, Anita
Rai, S. B.
JOURNAL OF LUMINESCENCE, 2009, 129 (06) : 629 - 633

← 1 2 3 4 5 →