Organolanthanide catalyzed regio- and stereoselective dimerization of terminal alkynes and polymerization of aromatic diynes

被引：86
|
作者：
Nishiura, M [1 ]
Hou, ZM [1 ]
机构：
[1] RIKEN, Organomet Chem Lab, Wako, Saitama 3510198, Japan
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 213卷 / 01期
关键词：
alkyne dimerization; diyne polymerization; lanthanide complex; alkynide complex; polyenyne;
D O I：
10.1016/j.molcata.2003.10.053
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This mini review describes recent advances in the application of organolanthanide complexes toward dimerization of terminal alkynes and polymerization of aromatic diynes. The regio- and stereoselectivity in these reactions can be controlled by tuning the ancillary ligands and the central metals of the catalysts. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：101 / 106
页数：6
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