Regio- and Stereoselective Copper-Catalyzed Addition of Aromatic and Aliphatic Thiols to Terminal and Internal Nonactivated Alkynes

被引：40
|
作者：
Trostyanskaya, Inna G. [1 ]
Beletskaya, Irina P. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
来源：
SYNLETT | 2012年 / 04期
关键词：
hydrothiolation; alkynes; copper catalyst; stereoselective anti-Markovnikov addition; isomerization; CROSS-COUPLING REACTIONS; FREE-RADICAL ADDITION; VINYL SULFIDES; OXIDATIVE ADDITION; ALKENYL SULFIDES; FACILE SYNTHESIS; ENOL THIOETHERS; ARYL SULFIDES; CARBON-SULFUR; C-S;
D O I：
10.1055/s-0031-1290345
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The CuI-catalyzed regio- and stereoselective hydrothiolation of terminal and internal alkynes affords (Z)-beta-alkenylsulfides. The following isomerization of the Z-isomers into E-isomers catalyzed by CuI is described.
引用
收藏
页码：535 / 540
页数：6
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