Preparation and properties of crystals and films of AgInSe2 and CuInSe2 ternary compounds and CuxAg1-xInSe2 solid solutions

被引：0
|
作者：
Bodnar', IV [1 ]
机构：
[1] Belarussian State Univ Informat Sci & Radio Engn, Minsk 220072, BELARUS
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2002年 / 47卷 / 12期
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D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure and transmission and reflection spectra near the fundamental absorption edge are investigated for the crystals and films of AgInSe2 and CuInSe2 ternary compounds and CuxAg1-xInSe2 solid solutions. The unit cell parameters, the positional parameter (which determines the position of the C atom relative to the A and Batoms in A(I)B(III)C(2)(VI) compounds), and bond lengths A-C and B-C are calculated. The band-gap is determined for the crystals; the energies of band-to-band transitions and the values of crystal and spin-orbit splitting are determined for the films. The results obtained for the films agree with the data for bulk crystals.
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页码：1790 / 1795
页数：6
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