NITRILOTRIS(METHYLENEPHOSPHONIC ACID) AS A NEW HIGHLY EFFICIENT AND RECYCLABLE BRONESTED ACID CATALYST FOR THE SYNTHESIS OF QUINOXALINE DERIVATIVES UNDER MILD AND GREEN CONDITIONS

被引:6
|
作者
Fathi, Safoura [1 ]
Sardarian, Ali Reza [1 ]
机构
[1] Shiraz Univ, Dept Chem, Coll Sci, Shiraz 75454, Iran
关键词
Nitrilotris(methylenephosphonic acid); 1,2-diamines; 1,2-diketones; quinoxalines; organocatalyst; recyclable catalyst; ALPHA-HYDROXY KETONES; SCHIFF-BASE COMPLEX; MOLECULAR-IODINE; AMMONIUM-NITRATE; OXIDATION; PROTOCOL; PYRIDOPYRAZINE; SYSTEM; SBA-15; WATER;
D O I
10.1080/10426507.2014.990017
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Nitrilotris(methylenephosphonic acid) has been introduced as a novel organocatalyst for the preparation of quinoxalines. It can efficiently catalyze the synthesis of quinoxaline derivatives from 1,2-diamines and 1,2-diketones under mild, efficient, and eco-friendly conditions. Excellent yields, very short reaction times, safety, and recyclability of the catalyst system are other features of the proposed method.
引用
收藏
页码:1471 / 1478
页数:8
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