Stereoselective synthesis of cyclometalated iridium(III) complexes: Characterization and photophysical properties

被引：33
|
作者：
Yang, Liangru [1 ,2 ]
von Zelewsky, Alex [1 ]
Nguyen, Huong P. [3 ]
Muller, Gilles [3 ]
Labat, Gael [4 ]
Stoeckli-Evans, Helen [4 ]
机构：
[1] Univ Fribourg, Dept Chem, CH-1700 Fribourg, Switzerland
[2] Henan Univ Technol, Sch Chem & Chem Engn, Zhengzhou 450001, Henan, Peoples R China
[3] San Jose State Univ, Dept Chem, San Jose, CA 95192 USA
[4] Univ Neuchatel, Inst Microtechnol, CH-2002 Neuchatel, Switzerland
来源：
INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 10期
关键词：
Irdium; Cyclometalated complexes; Stereoselective synthesis; Circular polarized luminescence; CIRCULARLY-POLARIZED LUMINESCENCE; LIGAND; PHOTOCHEMISTRY; CHIRALITY; RH(III);
D O I：
10.1016/j.ica.2008.10.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The stereoselective synthesis of a highly luminescent neutral Ir(III) complex comprising two bidentate chiral, cyclometalating phenylpyridine derivatives, and one acetylacetonate as ligands is described. The final complex and some intermediates were characterized by X-ray structural analysis, NMR-, CD-, and CPL-spectroscopy. (C) 2008 Published by Elsevier B.V.
引用
收藏
页码：3853 / 3856
页数：4
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