Stereoselective synthesis of cyclometalated iridium(III) complexes: Characterization and photophysical properties

被引：33

作者：

Yang, Liangru ^{[1
,2
]}

von Zelewsky, Alex ^{[1
]}

Nguyen, Huong P. ^{[3
]}

Muller, Gilles ^{[3
]}

Labat, Gael ^{[4
]}

Stoeckli-Evans, Helen ^{[4
]}

机构：

[1] Univ Fribourg, Dept Chem, CH-1700 Fribourg, Switzerland

[2] Henan Univ Technol, Sch Chem & Chem Engn, Zhengzhou 450001, Henan, Peoples R China

[3] San Jose State Univ, Dept Chem, San Jose, CA 95192 USA

[4] Univ Neuchatel, Inst Microtechnol, CH-2002 Neuchatel, Switzerland

来源：

INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 10期

关键词：

Irdium; Cyclometalated complexes; Stereoselective synthesis; Circular polarized luminescence; CIRCULARLY-POLARIZED LUMINESCENCE; LIGAND; PHOTOCHEMISTRY; CHIRALITY; RH(III);

D O I：

10.1016/j.ica.2008.10.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The stereoselective synthesis of a highly luminescent neutral Ir(III) complex comprising two bidentate chiral, cyclometalating phenylpyridine derivatives, and one acetylacetonate as ligands is described. The final complex and some intermediates were characterized by X-ray structural analysis, NMR-, CD-, and CPL-spectroscopy. (C) 2008 Published by Elsevier B.V.

引用

页码：3853 / 3856

页数：4

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