Photophysical and electrochemical properties of heteroleptic tris-cyclometalated iridium(III) complexes

被引：235
|
作者：
Dedeian, K [1 ]
Shi, JM [1 ]
Shepherd, N [1 ]
Forsythe, E [1 ]
Morton, DC [1 ]
机构：
[1] USA, Res Lab, Adelphi, MD 20783 USA
来源：
INORGANIC CHEMISTRY | 2005年 / 44卷 / 13期
关键词：
D O I：
10.1021/ic050324u
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Mixed (difluoro)phenylpyridine/(difluoro)phenylpyrazole tris-cyclometalated iridium complexes were prepared in order to study the effect of fluorination and the pyridine/pyrazole ratio on the emission and electrochemical properties. Increasing fluorination and replacement of pyridine by pyrazole both leads to a widening of the HOMO-LUMO gap and generally leads to a blue shift in emission.
引用
收藏
页码：4445 / 4447
页数：3
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