Photophysical and electrochemical properties of heteroleptic tris-cyclometalated iridium(III) complexes

被引：235

作者：

Dedeian, K ^{[1
]}

Shi, JM ^{[1
]}

Shepherd, N ^{[1
]}

Forsythe, E ^{[1
]}

Morton, DC ^{[1
]}

机构：

[1] USA, Res Lab, Adelphi, MD 20783 USA

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 13期

关键词：

D O I：

10.1021/ic050324u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mixed (difluoro)phenylpyridine/(difluoro)phenylpyrazole tris-cyclometalated iridium complexes were prepared in order to study the effect of fluorination and the pyridine/pyrazole ratio on the emission and electrochemical properties. Increasing fluorination and replacement of pyridine by pyrazole both leads to a widening of the HOMO-LUMO gap and generally leads to a blue shift in emission.

引用

页码：4445 / 4447

页数：3

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