Variational calculations for the energy levels of confined two-electron atomic systems

被引:67
|
作者
Saha, B
Mukherjee, TK
Mukherjee, PK [1 ]
Diercksen, GHF
机构
[1] Indian Assoc Cultivat Sci, Dept Spect, Kolkata 700032, W Bengal, India
[2] Max Planck Inst Astrophys, D-85741 Garching, Germany
关键词
confined atoms; variational calculations; Debye plasma;
D O I
10.1007/s00214-002-0389-z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An accurate variational calculation has been performed for the ground-state-energy values of confined two-electron isoelectronic series from He to Ar16+. The confinement is obtained by embedding the ion in an overall charge neutral environment like that of a plasma. The confinement potential is chosen as that of a screened Coulomb potential between charges, obtained from a Debye model. The wave function is expanded in terms of product basis sets involving interparticle coordinates. The energy levels are found to be less bound with an increase of the screening parameter and ultimately become unstable. One- and two-particle moments have been calculated for the first time under such screening. The study is expected to throw new light on the behavior of the energy levels of foreign atoms embedded in an overall neutral environment which can be treated like a plasma.
引用
收藏
页码:305 / 310
页数:6
相关论文
共 50 条
  • [31] Electron density analysis of two-electron systems confined by prolate spheroids with hard walls
    Yanajara-Parra, Heichi
    Corella-Madueno, Adalberto
    Adrian Duarte-Alcaraz, F.
    Vargas, Rubicelia
    Garza, Jorge
    JOURNAL OF PHYSICS COMMUNICATIONS, 2024, 8 (02):
  • [32] Correlation energy density functionals for two-electron systems
    Katriel, Jacob
    Roy, Sudip
    Springborg, Michael
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [33] PARTIAL VARIATIONAL CALCULATIONS ON PI-ELECTRON SYSTEMS - AN ATOMIC ANALOGUE
    STEWART, ET
    PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON, 1960, 75 (481): : 138 - 141
  • [34] Single ionization of one- and two-electron atomic systems by electron impact
    Berakdar, J
    Buckman, SJ
    PHYSICAL REVIEW A, 1996, 54 (06): : 5431 - 5434
  • [35] VARIATIONAL CALCULATIONS FOR QUARTET STATES OF 3-ELECTRON ATOMIC SYSTEMS
    HOLOIEN, E
    GELTMAN, S
    PHYSICAL REVIEW, 1967, 153 (01): : 81 - &
  • [36] Ab initio calculations of lower resonant states of two-electron systems
    A. A. Preobrazhenskaya
    S. O. Adamson
    D. D. Kharlampidi
    A. I. Dement’ev
    Russian Journal of Physical Chemistry B, 2016, 10 : 133 - 142
  • [37] Ab Initio Calculations of Lower Resonant States of Two-Electron Systems
    Preobrazhenskaya, A. A.
    Adamson, S. O.
    Kharlampidi, D. D.
    Dement'ev, A. I.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B, 2016, 10 (01) : 133 - 142
  • [38] Variational study of two-electron quantum dots
    Kandemir, BS
    PHYSICAL REVIEW B, 2005, 72 (16)
  • [39] Shannon information entropy in position space for two-electron atomic systems
    Lin, Chien-Hao
    Ho, Yew Kam
    CHEMICAL PHYSICS LETTERS, 2015, 633 : 261 - 264
  • [40] Precision XUV laser spectroscopy of atomic and molecular two-electron systems
    Hogervorst, W
    Eikema, KSE
    Reinhold, E
    Ubachs, W
    NUCLEAR PHYSICS A, 1998, 631 : 353C - 362C