Variational calculations for the energy levels of confined two-electron atomic systems

被引:67
|
作者
Saha, B
Mukherjee, TK
Mukherjee, PK [1 ]
Diercksen, GHF
机构
[1] Indian Assoc Cultivat Sci, Dept Spect, Kolkata 700032, W Bengal, India
[2] Max Planck Inst Astrophys, D-85741 Garching, Germany
关键词
confined atoms; variational calculations; Debye plasma;
D O I
10.1007/s00214-002-0389-z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An accurate variational calculation has been performed for the ground-state-energy values of confined two-electron isoelectronic series from He to Ar16+. The confinement is obtained by embedding the ion in an overall charge neutral environment like that of a plasma. The confinement potential is chosen as that of a screened Coulomb potential between charges, obtained from a Debye model. The wave function is expanded in terms of product basis sets involving interparticle coordinates. The energy levels are found to be less bound with an increase of the screening parameter and ultimately become unstable. One- and two-particle moments have been calculated for the first time under such screening. The study is expected to throw new light on the behavior of the energy levels of foreign atoms embedded in an overall neutral environment which can be treated like a plasma.
引用
收藏
页码:305 / 310
页数:6
相关论文
共 50 条
  • [21] Improved Le Sech wavefunctions for two-electron atomic systems
    Chauhan, Rabeet Singh
    Harbola, Manoj K.
    CHEMICAL PHYSICS LETTERS, 2015, 639 : 248 - 253
  • [22] Confined quantum systems: spectral properties of two-electron quantum dots
    Sako, T
    Diercksen, GHF
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2003, 15 (32) : 5487 - 5509
  • [23] Tsallisq-exponentials as atomic orbitals in two-electron systems
    Lombardo, Giuseppe Marcello
    INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2021, 121 (05)
  • [24] Confined two-electron systems: excited singlet and triplet S states
    H. E. Montgomery
    Vladimir I. Pupyshev
    Theoretical Chemistry Accounts, 2015, 134
  • [25] Confined two-electron systems: excited singlet and triplet S states
    Montgomery, H. E., Jr.
    Pupyshev, Vladimir I.
    THEORETICAL CHEMISTRY ACCOUNTS, 2014, 134 (01)
  • [26] Note on critical cage size for ionization of confined two-electron systems
    Díaz-García, C
    Cruz, SA
    PHYSICS LETTERS A, 2006, 353 (04) : 332 - 336
  • [27] Atomic and molecular two-electron systems in external laser fields
    Sandner, W
    Rottke, H
    Eichmann, U
    Seng, M
    Ludwig, H
    Rosen, C
    LASER PHYSICS, 1997, 7 (01) : 223 - 229
  • [28] Expectation values in one- and two-electron atomic systems
    Tsapline, B.
    CHEMICAL PHYSICS LETTERS, 1970, 6 (06) : 596 - 600
  • [29] The two-electron atomic systems. S-states
    Liverts, Evgeny Z.
    Barnea, Nir
    COMPUTER PHYSICS COMMUNICATIONS, 2010, 181 (01) : 206 - 212
  • [30] Confined variational calculations of low-energy electron-helium scattering
    Wan, J-Y
    Wu, M-S
    Zhang, J-Y
    Yan, Z-C
    PHYSICAL REVIEW A, 2021, 103 (04)