Chelating and bridging modes of coordination by 1,3-bis(pyrazol-1-yl)propane; Coexistence of discrete and polymeric metallosupramolecular isomers within the same crystal

被引：22
|
作者：
McMorran, DA [1 ]
Pfadenhauer, S [1 ]
Steel, PJ [1 ]
机构：
[1] Univ Canterbury, Dept Chem, Christchurch 1, New Zealand
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 2002年 / 55卷 / 08期
关键词：
D O I：
10.1071/CH02061
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
1,3-Bis(pyrazol-1-yl) propane (1) reacts with zinc acetate and cadmium nitrate to give tetrahedral [Zn(1)(OAc)(2)] and eight-coordinate [Cd(1)(2)(NO3)(2)]mononuclear complexes (2) and (3), respectively. Reaction with silver nitrate results in the formation of an intriguing complex (4) that consists of discrete M2L2 binuclear units stacked between [ML](n) polymeric chains.
引用
收藏
页码：519 / 522
页数：4
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