Chelating and bridging modes of coordination by 1,3-bis(pyrazol-1-yl)propane; Coexistence of discrete and polymeric metallosupramolecular isomers within the same crystal

被引：22

作者：

McMorran, DA ^{[1
]}

Pfadenhauer, S ^{[1
]}

Steel, PJ ^{[1
]}

机构：

[1] Univ Canterbury, Dept Chem, Christchurch 1, New Zealand

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2002年 / 55卷 / 08期

关键词：

D O I：

10.1071/CH02061

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1,3-Bis(pyrazol-1-yl) propane (1) reacts with zinc acetate and cadmium nitrate to give tetrahedral [Zn(1)(OAc)(2)] and eight-coordinate [Cd(1)(2)(NO3)(2)]mononuclear complexes (2) and (3), respectively. Reaction with silver nitrate results in the formation of an intriguing complex (4) that consists of discrete M2L2 binuclear units stacked between [ML](n) polymeric chains.

引用

页码：519 / 522

页数：4

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