The standard potentials of the electrode ''dissolved atomic mercury/dissolved mercury ions''

被引：10
|
作者：
Scholz, F [1 ]
Lovric, M [1 ]
机构：
[1] RUDJER BOSKOVIC INST,CTR MARINE RES,HR-10000 ZAGREB,CROATIA
来源：
ELECTROANALYSIS | 1996年 / 8卷 / 11期
关键词：
standard potentials; redox electrode; mercury;
D O I：
10.1002/elan.1140081118
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The standard potentials of the redox electrodes ''dissolved atomic mercury/dissolved mercury ions'' are calculated to be E(0)(Hg-0/Hg2+) = 0.661V (vs. SHE) and E(0)(Hg-0/Hg-2(2+)) = 0.410V (vs. SHE). The standard potential of the electrode ''metallic mercury/dissolved mercury ions'' E(0)(Hg/Hg2+) = 0.8535V (vs. SHE) is the formal potential of the electrode ''dissolved atomic mercury/dissolved mercury ions'' at potentials E(0)(Hg-0/Hg2+) and E(0)(Hg-0/Hg-2(2+)) have to be used or the relation between them and E(0)(Hg/Hg2+) and E(0)(Hg/Hg-2(2+)) has to be taken into account.
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页码：1075 / 1076
页数：2
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