Excess Molar Enthalpies of Diethyl Malonate plus (Methanol, plus Ethanol,+1-Propanol, and+2-Propanol) at T = (288.2, 298.2, 313.2, and 328.2) K and p=101.3 kPa

被引：6
|
作者：
Wang, Yihe [1 ]
Gao, Hui [1 ]
Yan, Weidong [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2010年 / 55卷 / 01期
关键词：
ALPHA-ARYLATION; MIXTURES; ALKANOLS;
D O I：
10.1021/je9003806
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Excess molar enthalpies for four binary systems of diethyl malonate + (methanol, + ethanol, + 1-propanol, and + 2-propanol) at T = (288.2, 298.2, 313.2, and 328.2) K and p = 101.3 kPa were determined by using a flow-mixing isothermal microcalorimeter. The excess molar enthalpies increase with temperature and the molecular size of the alcohols. The experimental data were correlated by using the Redlich-Kister equation and two local-composition models (NRTL and UNIQUAC). The densities of the diethyl malonate at different temperature were measured by using a vibrating-tube densimeter.
引用
收藏
页码：381 / 384
页数：4
相关论文
共 50 条
  • [41] The enthalpies and entropies of pefloxacin dissolution in methanol, ethanol, 1-Propanol, 2-Propanol, acetone, and chloroform at 293.15–323.15 K
    C. -L. Zhang
    S. -J. Cui
    Y. Wang
    Russian Journal of Physical Chemistry A, 2012, 86 : 1953 - 1956
  • [42] SOLUBILITY OF HELIUM IN METHANOL PLUS WATER, ETHANOL PLUS WATER, 1-PROPANOL PLUS WATER, AND 2-PROPANOL PLUS WATER SOLUTIONS AT 25-DEGREES-C
    YAMAMOTO, H
    ICHIKAWA, K
    TOKUNAGA, J
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1994, 39 (01): : 155 - 157
  • [43] Excess molar volumes of 1-propanol plus formamide, plus N-methylformamide, plus N,N-dimethylformamide at 303.15 K
    Saleh, MA
    Begum, S
    Uddin, MH
    JOURNAL OF MOLECULAR LIQUIDS, 2001, 94 (02) : 155 - 161
  • [44] vapor-liquid equilibrium for the systems trans-2-butene plus methanol, plus 1-propanol,plus 2-propanol, plus 2-butanol, and plus 2-methyl-2-propanol at 364.5 K
    Roininen, Jonas
    Uusi-Kyyny, Petri
    Pokki, Juha-Pekka
    Pakkanen, Minna
    Alopaeus, Ville
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2008, 53 (02): : 607 - 612
  • [45] Excess molar enthalpies of ternary mixtures for propanone or benzene plus aniline plus 2-methyl-1-propanol and of binary mixtures for propanone or aniline plus 2-methyl-1-propanol at 298.15 K
    Nagata, I
    Tamura, K
    Miyai, K
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (06): : 1350 - 1354
  • [46] Isothermal vapor liquid equilibrium for 2-methylpropene plus methanol, plus 1-propanol, plus 2-propanol, plus 2-butanol, and plus 2-methyl-2-propanol binary systems at 364.5 K
    Hynynen, K
    Uusi-Kyyny, P
    Pokki, JP
    Pakkanen, M
    Aittamaa, J
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2006, 51 (02): : 562 - 568
  • [47] Excess molar enthalpies for ternary mixtures of (methanol or ethanol plus water plus tributyl phosphate) at T=298.15 K
    Liu, Hong-Li
    Liu, Shi-Jun
    Chen, Qi-Yuan
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2012, 107 (02) : 837 - 841
  • [48] Solubility of dimethyl fumarate in water plus (methanol, ethanol, 1-propanol) from (278.15 to 333.15) K
    Kai, Yumei
    Hu, Yonghong
    Tang, Rongrong
    Meng, Zhongbin
    Yang, Wenge
    FLUID PHASE EQUILIBRIA, 2013, 344 : 19 - 26
  • [49] Solubilities of Cefepime Hydrochloride in Water plus (Ethanol, 1-Propanol, or 2-Propanol) from (278.15 to 308.15) K
    Li, Yu
    Xu, Li
    Wang, Fu-an
    Jin, Hai-hong
    Ren, Bao-zeng
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2010, 55 (09): : 4098 - 4103
  • [50] Excess molar enthalpies and volumes of binary mixtures of two hydrofluoroethers with hexane, or benzene, or ethanol, or 1-propanol, or 2-butanone at T=298.15 K
    Ogawa, H
    Karashima, S
    Takigawa, T
    Murakami, S
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2003, 35 (05): : 763 - 774
12345