Excess Molar Enthalpies of Diethyl Malonate plus (Methanol, plus Ethanol,+1-Propanol, and+2-Propanol) at T = (288.2, 298.2, 313.2, and 328.2) K and p=101.3 kPa

被引：6
|
作者：
Wang, Yihe [1 ]
Gao, Hui [1 ]
Yan, Weidong [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2010年 / 55卷 / 01期
关键词：
ALPHA-ARYLATION; MIXTURES; ALKANOLS;
D O I：
10.1021/je9003806
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Excess molar enthalpies for four binary systems of diethyl malonate + (methanol, + ethanol, + 1-propanol, and + 2-propanol) at T = (288.2, 298.2, 313.2, and 328.2) K and p = 101.3 kPa were determined by using a flow-mixing isothermal microcalorimeter. The excess molar enthalpies increase with temperature and the molecular size of the alcohols. The experimental data were correlated by using the Redlich-Kister equation and two local-composition models (NRTL and UNIQUAC). The densities of the diethyl malonate at different temperature were measured by using a vibrating-tube densimeter.
引用
收藏
页码：381 / 384
页数：4
相关论文
共 50 条
  • [21] Excess Molar Volumes and Partial Molar Volumes of Binary Systems (Ionic Liquid plus Methanol or Ethanol or 1-Propanol) at T = (298.15, 303.15 and 313.15) K
    Sibiya, Precious N.
    Deenadayalu, Nirmala
    SOUTH AFRICAN JOURNAL OF CHEMISTRY-SUID-AFRIKAANSE TYDSKRIF VIR CHEMIE, 2009, 62 : 20 - 25
  • [22] Excess molar enthalpies for di-n-butylether plus 1-propanol plus n-decane at 298.15 and 308.15 K
    Segade, L
    Jiménez, E
    Franjo, C
    Legido, JL
    Andrade, MIP
    FLUID PHASE EQUILIBRIA, 1999, 156 (1-2) : 149 - 159
  • [23] Excess molar enthalpies for di-n-butyl ether plus 1-propanol plus n-octane at 298.15 K
    Jimenez, E
    Franjo, C
    Segade, L
    Legido, JL
    Andrade, MIP
    FLUID PHASE EQUILIBRIA, 1997, 133 (1-2) : 179 - 185
  • [24] Excess molar volumes of 1-propanol plus n-polyethers at 298.15 K
    Serna, A
    delaFuente, IG
    Gonzalez, JA
    Cobos, JC
    FLUID PHASE EQUILIBRIA, 1997, 133 (1-2) : 187 - 192
  • [25] THE MOLAR EXCESS-ENTHALPIES AND VOLUMES OF 3 1-ALKYNES+1-PROPANOL AND+2-PROPANOL MIXTURES AT 298.15-K
    LETCHER, TM
    MERCERCHALMERS, JD
    GOVENDER, PU
    RADLOFF, SE
    FLUID PHASE EQUILIBRIA, 1993, 91 (02) : 313 - 320
  • [26] EXCESS MOLAR ENTHALPIES OF ACETONE PLUS WATER, CYCLOHEXANE, METHANOL, 1-PROPANOL, 2-PROPANOL, 1-BUTANOL AND 1-PENTANOL AT 283.15, 298.15, 323.15, 343.15 AND 363.15K
    LOWEN, B
    SCHULZ, S
    THERMOCHIMICA ACTA, 1995, 262 : 69 - 82
  • [27] DENSITIES AND EXCESS MOLAR VOLUMES FOR BINARY SOLUTION OF WATER plus ETHANOL, plus METHANOL AND plus PROPANOL FROM (283.15 TO 313.15) K
    Shalmashi, A.
    Amani, F.
    LATIN AMERICAN APPLIED RESEARCH, 2014, 44 (02) : 163 - 163
  • [28] EXCESS MOLAR ENTHALPIES OF BINARY AND TERNARY MIXTURES FOR 1-PROPANOL PLUS 3-PENTANONE PLUS 1-HEXANOL OR PLUS 1-HEPTANOL AT 298.15 K
    LOPEZ, M
    LEGIDO, JL
    ROMANI, L
    PELETEIRO, J
    ANDRADE, MIP
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1993, 38 (02): : 238 - 241
  • [29] Densities and Excess Molar Volume for the Ternary Systems (1-Butyl-3-methylimidazolium methyl sulphate plus Nitromethane plus Methanol or Ethanol or 1-Propanol) at T = (303.15 and 313.15) K
    Bahadur, Indra
    Deenadayalu, Nirmala
    SOUTH AFRICAN JOURNAL OF CHEMISTRY-SUID-AFRIKAANSE TYDSKRIF VIR CHEMIE, 2013, 66 : 200 - 206
  • [30] Isobaric Binary Vapor-Liquid Equilibrium of Ethanol plus Glycerol and 1-Propanol + Glycerol Systems at 16.0 and 101.3 kPa
    Batutah, Moh Arif
    Kuswandi, Kuswandi
    Wibawa, Gede
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2020, 65 (08): : 3802 - 3807
12345